Article(id=1322943083855356393, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200296, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1587744000000, receivedDateStr=2020-04-25, revisedDate=1589472000000, revisedDateStr=2020-05-15, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343810284, onlineDateStr=2026-10-30, pubDate=1616169600000, pubDateStr=2021-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343810284, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343810284, creator=13701087609, updateTime=1793343810284, updator=13701087609, issue=Issue{id=1322942495801356913, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='3', pageStart='441', pageEnd='604', issueExtLink='null', onlineDate='null', pubDate='1616169600000', pubDateStr='2021-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343670081, creator='13701087609', updateTime=1793345495044, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950150322258738, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950150322258739, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=544, endPage=550, ext={EN=ArticleExt(id=1322943084006351338, articleId=1322943083855356393, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Photocatalytic Performance of Zinc Oxide Nanoparticles Synthesized by Ultrasonic Atomization-Assisted Microwave Method, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Zinc oxide (ZnO) is widely used as a photocatalyst in the treatment of organic pollutants in wastewater due to its wide bandgap, high photocatalytic efficiency, and stable chemical properties. Based on the results by X-ray diffraction and transmission electric microscopy, synthesized ZnO remains a highly disordered structure because the crystallization of ZnO is suppressed by ultrasonic atomization. Amorphous ZnO nanoparticles were synthesized by a ultrasonic atomization-assisted microwave sintering method. Amorphous ZnO nanoparticles with a highly disordered structure enhance the absorption at a wavelength of 300 nm. The UV absorption of amorphous ZnO nanoparticles shifts to the lower energy side and is greater than that of crystal ZnO nanoparticles. The forbidden bandwidth of amorphous ZnO nanoparticles reduces to 3.17 eV. The photocatalytic efficiency of amorphous ZnO nanoparticles is improved, and the photocatalytic degradation efficiency of amorphous ZnO nanoparticles on Rhodamine B (RB) is 37% greater than that of crystal ZnO nanoparticles. Ultrasonic atomization-assisted microwave sintering method could be an effective method for preparing amorphous ZnO nanoparticles at a low temperature and a low energy consumption. Amorphous ZnO nanoparticles are a highly efficient photocatalyst. However, since the photocatalytic efficiency of amorphous ZnO nanoparticles could decrease with increasing the catalytic cycles, the stability and dispersion of amorphous ZnO nanoparticles should be thus further improved.

, authors=Qing LIN, Lingling LI, Wei WANG, Xiaojuan ZHANG, Lingyun HAO, authorsList=Qing LIN, Lingling LI, Wei WANG, Xiaojuan ZHANG, Lingyun HAO, authorCompany=null, correspAuthors=Lingyun HAO, authorNote=

LIN Qing (1983-), male, Ph.D., Associate Professor. E-mail:

, correspAuthorsNote=
HAO Lingyun (1966-), female, Ph. D., Professor. E-mail:
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氧化锌(ZnO)具有宽带隙、高光催化效率和稳定的化学性质,已成为处理水体中有机污染物的常用材料。采用超声雾化辅助微波法成功合成了ZnO纳米颗粒,XRD图谱和TEM照片表明超声雾化抑制了ZnO结晶,其结构为无序状,得到的ZnO纳米颗粒为非晶态。非晶态ZnO纳米颗粒紫外最强吸收峰为300 nm,紫外吸收边发生红移,禁带宽度降至3.17 eV,紫外吸收率高于晶态ZnO颗粒,光催化活性显著提高,对Rhodamine B催化降解效率较晶态ZnO颗粒高出37%。超声雾化辅助微波法是一种低温、低能耗合成非晶态ZnO纳米颗粒的方法,合成的ZnO纳米颗粒光催化活性高,但其光催化效率随催化循环次数增加而降低,其分散性和稳定性有待进一步改善。

, authors=林青, 李玲玲, 王威, 张小娟, 郝凌云, authorsList=林青, 李玲玲, 王威, 张小娟, 郝凌云, authorCompany=null, correspAuthors=郝凌云, authorNote=

林青(1983—),男,博士,副教授。

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郝凌云(1966—),女,博士,教授。
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超声雾化辅助微波法合成氧化锌纳米颗粒及其光催化性能
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林青 , 李玲玲 , 王威 , 张小娟 , 郝凌云
硅酸盐学报 | 2021,49(3): 544-550
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硅酸盐学报 | 2021 , 49 (3) : 544 -550
超声雾化辅助微波法合成氧化锌纳米颗粒及其光催化性能
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林青 , 李玲玲, 王威, 张小娟, 郝凌云
作者信息
  • 金陵科技学院材料工程学院,南京 211169
通讯作者:
郝凌云(1966—),女,博士,教授。
作者简介:

林青(1983—),男,博士,副教授。

Photocatalytic Performance of Zinc Oxide Nanoparticles Synthesized by Ultrasonic Atomization-Assisted Microwave Method
Qing LIN , Lingling LI, Wei WANG, Xiaojuan ZHANG, Lingyun HAO
Affiliations
  • School of Materials Engineering, Jinling Institute of Technology, Nanjing 211169, China
  • Corresponding Author:
    HAO Lingyun (1966-), female, Ph. D., Professor. E-mail:

    LIN Qing (1983-), male, Ph.D., Associate Professor. E-mail:

出版时间: 2021-03-20 doi: 10.14062/j.issn.0454-5648.20200296
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氧化锌(ZnO)具有宽带隙、高光催化效率和稳定的化学性质,已成为处理水体中有机污染物的常用材料。采用超声雾化辅助微波法成功合成了ZnO纳米颗粒,XRD图谱和TEM照片表明超声雾化抑制了ZnO结晶,其结构为无序状,得到的ZnO纳米颗粒为非晶态。非晶态ZnO纳米颗粒紫外最强吸收峰为300 nm,紫外吸收边发生红移,禁带宽度降至3.17 eV,紫外吸收率高于晶态ZnO颗粒,光催化活性显著提高,对Rhodamine B催化降解效率较晶态ZnO颗粒高出37%。超声雾化辅助微波法是一种低温、低能耗合成非晶态ZnO纳米颗粒的方法,合成的ZnO纳米颗粒光催化活性高,但其光催化效率随催化循环次数增加而降低,其分散性和稳定性有待进一步改善。

氧化锌  /  非晶态  /  超声雾化  /  光催化

Zinc oxide (ZnO) is widely used as a photocatalyst in the treatment of organic pollutants in wastewater due to its wide bandgap, high photocatalytic efficiency, and stable chemical properties. Based on the results by X-ray diffraction and transmission electric microscopy, synthesized ZnO remains a highly disordered structure because the crystallization of ZnO is suppressed by ultrasonic atomization. Amorphous ZnO nanoparticles were synthesized by a ultrasonic atomization-assisted microwave sintering method. Amorphous ZnO nanoparticles with a highly disordered structure enhance the absorption at a wavelength of 300 nm. The UV absorption of amorphous ZnO nanoparticles shifts to the lower energy side and is greater than that of crystal ZnO nanoparticles. The forbidden bandwidth of amorphous ZnO nanoparticles reduces to 3.17 eV. The photocatalytic efficiency of amorphous ZnO nanoparticles is improved, and the photocatalytic degradation efficiency of amorphous ZnO nanoparticles on Rhodamine B (RB) is 37% greater than that of crystal ZnO nanoparticles. Ultrasonic atomization-assisted microwave sintering method could be an effective method for preparing amorphous ZnO nanoparticles at a low temperature and a low energy consumption. Amorphous ZnO nanoparticles are a highly efficient photocatalyst. However, since the photocatalytic efficiency of amorphous ZnO nanoparticles could decrease with increasing the catalytic cycles, the stability and dispersion of amorphous ZnO nanoparticles should be thus further improved.

zinc oxide  /  amorphous  /  ultrasonic atomization  /  photocatalysis
林青, 李玲玲, 王威, 张小娟, 郝凌云. 超声雾化辅助微波法合成氧化锌纳米颗粒及其光催化性能. 硅酸盐学报, 2021 , 49 (3) : 544 -550 . DOI: 10.14062/j.issn.0454-5648.20200296
Qing LIN, Lingling LI, Wei WANG, Xiaojuan ZHANG, Lingyun HAO. Photocatalytic Performance of Zinc Oxide Nanoparticles Synthesized by Ultrasonic Atomization-Assisted Microwave Method[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (3) : 544 -550 . DOI: 10.14062/j.issn.0454-5648.20200296
  • 国家自然科学基金青年基金(61804069)
  • 江苏省自然科学基金面上项目(BK20191112)
  • 江苏省高校优秀中青年教师和校长境外研修计划(2019年度)
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2021年第49卷第3期
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doi: 10.14062/j.issn.0454-5648.20200296
  • 接收时间:2020-04-25
  • 首发时间:2026-10-30
  • 出版时间:2021-03-20
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  • 收稿日期:2020-04-25
  • 修回日期:2020-05-15
基金
国家自然科学基金青年基金(61804069)
江苏省自然科学基金面上项目(BK20191112)
江苏省高校优秀中青年教师和校长境外研修计划(2019年度)
作者信息
    金陵科技学院材料工程学院,南京 211169

通讯作者:

郝凌云(1966—),女,博士,教授。
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2种不同金属材料的力学参数
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属数
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genus
种数
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species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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