Article(id=1322917095788388963, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322917095268295267, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200293, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1587571200000, receivedDateStr=2020-04-23, revisedDate=1589212800000, revisedDateStr=2020-05-12, acceptedDate=null, acceptedDateStr=null, onlineDate=1793337614246, onlineDateStr=2026-10-30, pubDate=1608393600000, pubDateStr=2020-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793337614246, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793337614246, creator=13701087609, updateTime=1793337614246, updator=13701087609, issue=Issue{id=1322917095268295267, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='12', pageStart='1865', pageEnd='2010', issueExtLink='null', onlineDate='null', pubDate='1608393600000', pubDateStr='2020-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793337614123, creator='13701087609', updateTime=1793345927101, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951962475507806, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322917095268295267, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951962475507807, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322917095268295267, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1982, endPage=1987, ext={EN=ArticleExt(id=1322917095947772516, articleId=1322917095788388963, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Y2O3 Powder on Properties of Corundum Refractory Printed by Layered Extrusion Printing, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

A ceramic slurry with a solid content of 57% (in volume fraction) was firstly prepared with α-Al2O3 of 92% (mass fraction) and silica fume of 8% as main raw materials, aluminum dihydrogen phosphate of 2.5% as a binder and sodium hexametaphosphate of 0.2% as a dispersant in the presence of Y2O3, and then the formed specimen was sintered at 1 600 ℃ for 3 h. The results show that the addition of Y2O3 has little effect on the printing properties of ceramic slurry. At high temperatures, Y2O3 reacts with Al2O3 to form YAG, and promotes the reaction of Al2O3 with SiO2 in the specimen, thus increasing the specimen strength. A rate of the properties change after sintering decreases, and even the slag resistance decreases when the amount of Y2O3 addition exceeds 1.2%. The cold compressive strength is 230.2 MPa at the optimal amount of Y2O3 addition of 1.2%. For slag resistance, in addition to the densification of the high melting point YAG phase and the solid phase, a dense protective layer is formed on the inner wall of the crucible, thus enhancing the resistance to the penetration of glass melt. It is indicated that the addition of Y2O3 is beneficial to printing the specimens with a high strength and a good slag resistance.

, authors=Zhenfei YU1, Daoyuan YANG1, Huiyu YUAN1, Junyan CUI1, Gang SHAO1, Lin YUAN2, Jianhui HU2, Suping SHANG3, authorsList=Zhenfei YU, Daoyuan YANG, Huiyu YUAN, Junyan CUI, Gang SHAO, Lin YUAN, Jianhui HU, Suping SHANG, authorCompany=null, correspAuthors=Daoyuan YANG, authorNote=

YU Zhenfei (1993-), male, Master candidate. E-mail:

, correspAuthorsNote=
YANG Daoyuan (1968-), female, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322917096321065573, articleId=1322917095788388963, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=Y2O3对刚玉质耐火材料3D打印浆料及制品性能的影响, columnId=0, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

以α-Al2O3[92%(质量分数)]和硅灰(8%)为原料,外加磷酸二氢铝结合剂(2.5%),六偏磷酸钠分散剂(0.2%),制备出固含量57%(体积分数)的浆料,成形后经1 600 ℃保温3 h烧结。结果表明:Y2O3的加入,对陶瓷浆料的打印性能影响较小,在高温下,Y2O3与Al2O3反应生成YAG,并促进样品中Al2O3与SiO2的反应,提高样品强度。当加入量超过1.2%后,烧后性能变化速率减缓,甚至抗渣性有降低的趋势,因此,Y2O3最佳加入量为1.2%,此时,抗压强度230.2 MPa,抗渣方面,除形成高熔点YAG相和固相密实化外,还在坩埚内璧形成致密防护层,抗玻璃熔体渗透增强。证实了加入Y2O3粉对打印高强度和抗渣性良好的样品有利。

, authors=于振飞1, 杨道媛1, 原会雨1, 崔俊艳1, 邵刚1, 袁林2, 胡建辉2, 尚素平3, authorsList=于振飞, 杨道媛, 原会雨, 崔俊艳, 邵刚, 袁林, 胡建辉, 尚素平, authorCompany=null, correspAuthors=杨道媛, authorNote=

于振飞(1993—),男,硕士研究生。

, correspAuthorsNote=
杨道媛(1968—),女,博士,教授。
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于振飞(1993—),男,硕士研究生。

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Y2O3对刚玉质耐火材料3D打印浆料及制品性能的影响
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于振飞 1 , 杨道媛 1 , 原会雨 1 , 崔俊艳 1 , 邵刚 1 , 袁林 2 , 胡建辉 2 , 尚素平 3
硅酸盐学报 | 2020,48(12): 1982-1987
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硅酸盐学报 | 2020 , 48 (12) : 1982 -1987
Y2O3对刚玉质耐火材料3D打印浆料及制品性能的影响
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于振飞1 , 杨道媛1 , 原会雨1, 崔俊艳1, 邵刚1, 袁林2, 胡建辉2, 尚素平3
作者信息
  • 1.郑州大学材料科学与工程学院,郑州,450001
  • 2.瑞泰科技股份有限公司,北京,100024
  • 3.河南豫科光学科技股份有限公司,郑州,450001
通讯作者:
杨道媛(1968—),女,博士,教授。
作者简介:

于振飞(1993—),男,硕士研究生。

Effect of Y2O3 Powder on Properties of Corundum Refractory Printed by Layered Extrusion Printing
Zhenfei YU1 , Daoyuan YANG1 , Huiyu YUAN1, Junyan CUI1, Gang SHAO1, Lin YUAN2, Jianhui HU2, Suping SHANG3
Affiliations
  • 1.School of materials science and engineering, Zhengzhou University, Zhengzhou 450001, China
  • 2.Ruitai Materials Technology Co., Ltd, Beijing 100024, China
  • 3.Henan Yuke Optical Technology Co., Ltd, Zhengzhou 450001, China
  • Corresponding Author:
    YANG Daoyuan (1968-), female, Ph.D., Professor. E-mail:

    YU Zhenfei (1993-), male, Master candidate. E-mail:

出版时间: 2020-12-20 doi: 10.14062/j.issn.0454-5648.20200293
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以α-Al2O3[92%(质量分数)]和硅灰(8%)为原料,外加磷酸二氢铝结合剂(2.5%),六偏磷酸钠分散剂(0.2%),制备出固含量57%(体积分数)的浆料,成形后经1 600 ℃保温3 h烧结。结果表明:Y2O3的加入,对陶瓷浆料的打印性能影响较小,在高温下,Y2O3与Al2O3反应生成YAG,并促进样品中Al2O3与SiO2的反应,提高样品强度。当加入量超过1.2%后,烧后性能变化速率减缓,甚至抗渣性有降低的趋势,因此,Y2O3最佳加入量为1.2%,此时,抗压强度230.2 MPa,抗渣方面,除形成高熔点YAG相和固相密实化外,还在坩埚内璧形成致密防护层,抗玻璃熔体渗透增强。证实了加入Y2O3粉对打印高强度和抗渣性良好的样品有利。

刚玉质耐火材料  /  氧化钇粉  /  分层挤出打印  /  强度  /  抗渣性

A ceramic slurry with a solid content of 57% (in volume fraction) was firstly prepared with α-Al2O3 of 92% (mass fraction) and silica fume of 8% as main raw materials, aluminum dihydrogen phosphate of 2.5% as a binder and sodium hexametaphosphate of 0.2% as a dispersant in the presence of Y2O3, and then the formed specimen was sintered at 1 600 ℃ for 3 h. The results show that the addition of Y2O3 has little effect on the printing properties of ceramic slurry. At high temperatures, Y2O3 reacts with Al2O3 to form YAG, and promotes the reaction of Al2O3 with SiO2 in the specimen, thus increasing the specimen strength. A rate of the properties change after sintering decreases, and even the slag resistance decreases when the amount of Y2O3 addition exceeds 1.2%. The cold compressive strength is 230.2 MPa at the optimal amount of Y2O3 addition of 1.2%. For slag resistance, in addition to the densification of the high melting point YAG phase and the solid phase, a dense protective layer is formed on the inner wall of the crucible, thus enhancing the resistance to the penetration of glass melt. It is indicated that the addition of Y2O3 is beneficial to printing the specimens with a high strength and a good slag resistance.

corundum refractories  /  yttrium oxide powder  /  layered extrusion printing  /  strength  /  slag resistance
于振飞, 杨道媛, 原会雨, 崔俊艳, 邵刚, 袁林, 胡建辉, 尚素平. Y2O3对刚玉质耐火材料3D打印浆料及制品性能的影响. 硅酸盐学报, 2020 , 48 (12) : 1982 -1987 . DOI: 10.14062/j.issn.0454-5648.20200293
Zhenfei YU, Daoyuan YANG, Huiyu YUAN, Junyan CUI, Gang SHAO, Lin YUAN, Jianhui HU, Suping SHANG. Effect of Y2O3 Powder on Properties of Corundum Refractory Printed by Layered Extrusion Printing[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (12) : 1982 -1987 . DOI: 10.14062/j.issn.0454-5648.20200293
  • 科技部国家重点研发专项(2017YFB0310701)
  • 河南省科技创新杰出人才基金(17420051001)
  • 郑州市“智汇郑州”急需紧缺人才基金和郑州市重大专项(2019CXZX0066)
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文章信息
doi: 10.14062/j.issn.0454-5648.20200293
  • 接收时间:2020-04-23
  • 首发时间:2026-10-30
  • 出版时间:2020-12-20
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  • 收稿日期:2020-04-23
  • 修回日期:2020-05-12
基金
科技部国家重点研发专项(2017YFB0310701)
河南省科技创新杰出人才基金(17420051001)
郑州市“智汇郑州”急需紧缺人才基金和郑州市重大专项(2019CXZX0066)
作者信息
    1.郑州大学材料科学与工程学院,郑州,450001
    2.瑞泰科技股份有限公司,北京,100024
    3.河南豫科光学科技股份有限公司,郑州,450001

通讯作者:

杨道媛(1968—),女,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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