Article(id=1322942971221516950, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942385474384734, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200279, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1586966400000, receivedDateStr=2020-04-16, revisedDate=1589558400000, revisedDateStr=2020-05-16, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343783430, onlineDateStr=2026-10-30, pubDate=1611072000000, pubDateStr=2021-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343783430, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343783430, creator=13701087609, updateTime=1793343783430, updator=13701087609, issue=Issue{id=1322942385474384734, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='1', pageStart='1', pageEnd='210', issueExtLink='null', onlineDate='null', pubDate='1611072000000', pubDateStr='2021-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343643777, creator='13701087609', updateTime=1793345438198, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322949911880282449, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942385474384734, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322949911880282450, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942385474384734, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=113, endPage=125, ext={EN=ArticleExt(id=1322942971431232151, articleId=1322942971221516950, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Doping Modification on PrBaCo₂O_5+δ Double Perovskite Cathode for Solid Oxide Fuel Cell, columnId=1322942386086753121, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on SOFC, runingTitle=null, highlight=null, articleAbstract=

The performance of solid oxide fuel cell (SOFC) as a clean and efficient energy conversion device is often restricted due to the oxygen reduction reaction at cathode. As a potential cathode electrocatalyst, cobalt based double perovskite oxide, namely PrBaCo₂O_5+δ, has a high oxygen surface exchange coefficient and a great bulk diffusion coefficient. However, the physical and chemical properties (i.e., thermal expansion behavior) should be optimized to improve the electrochemical activity and durability as applying PrBaCo₂O_5+δ into SOFC. Therefore, recent work is devoted to modifying PrBaCo₂O_5+δ by element doping. This review summarized various element doping approaches, i.e., doping to the Pr site, Ba site, Co site, and O site. In addition, the doping effect on the PrBaCo₂O_5+δ properties (i.e., phase structure, oxygen nonstoichiometry δ, electronic conductivity, oxygen transport properties and electrochemical performances) was also discussed.

, authors=Yanhong WAN, Xianze ZOU, Shaowei ZHANG, Changrong XIA, authorsList=Yanhong WAN, Xianze ZOU, Shaowei ZHANG, Changrong XIA, authorCompany=null, correspAuthors=Changrong XIA, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322942971712250520, articleId=1322942971221516950, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=固体氧化物燃料电池双钙钛矿阴极材料PrBaCo₂O_5+δ的掺杂改性, columnId=1322942387823194979, journalTitle=硅酸盐学报, columnName=SOFC专题, runingTitle=null, highlight=null, articleAbstract=

固体氧化物燃料电池（SOFC）是一种清洁、高效的能量转换装置，其性能受制于阴极的氧还原反应，钴基双钙钛矿氧化物PrBaCo₂O_5+δ具有较高的氧表面交换系数和体扩散系数，是近年来备受重视的阴极催化材料。然而，PrBaCo₂O_5+δ在SOFC中的应用受到热膨胀匹配性差等的制约，为此，大量的工作研究了PrBaCo₂O_5+δ的掺杂改性。本文综述了各种掺杂研究，按照掺杂位置分别总结了Pr位、Ba位、Co位和O位的掺杂元素和掺杂量，结合钙钛矿的容忍因子，讨论了掺杂对PrBaCo₂O_5+δ性能的影响，包括晶体结构、氧的非化学计量δ、电导率、热膨胀系数、氧传输性能和电化学性能等。

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WAN Yanhong (1992-), Female, Doctoral candidate. E-mail: yhwan@mail.ustc.edu.cn

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WAN Yanhong (1992-), Female, Doctoral candidate. E-mail: yhwan@mail.ustc.edu.cn

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万艳红（1992—），女，博士研究生。

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万艳红（1992—），女，博士研究生。

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