Article(id=1322636320237797660, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636274364698818, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200237, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1585584000000, receivedDateStr=2020-03-31, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1793270672138, onlineDateStr=2026-10-29, pubDate=1605801600000, pubDateStr=2020-11-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793270672138, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793270672138, creator=13701087609, updateTime=1793270672138, updator=13701087609, issue=Issue{id=1322636274364698818, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='11', pageStart='1689', pageEnd='1864', issueExtLink='null', onlineDate='null', pubDate='1605801600000', pubDateStr='2020-11-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793270661202, creator='13701087609', updateTime=1793277186220, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663642319930111, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636274364698818, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663642319930112, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636274364698818, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1716, endPage=1721, ext={EN=ArticleExt(id=1322636320640450845, articleId=1322636320237797660, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Adsorption of Superplasticizer and its Effect on Viscosity of Cement-Silica Fume Paste, columnId=1322636275505549507, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue for Ultra-high Performance Concrete Ⅱ, runingTitle=null, highlight=null, articleAbstract=

To improve the workability of ultra-high performance concrete (UHPC), the effect of superplasticizers (i.e., carboxylic-superplasticizer and phosphonic-superplasticsizer) on the rheological properties of cement/silica fume pastes with a low water-binder ratio was investigated, and the adsorption behavior of the superplasticizers in paste, the packing density and the viscosity of interstitial solution were analyzed. The results show that the superplasticizers have a preferential adsorption behavior on different particle surfaces, and carboxylic-superplasticizer has a superior adsorption ability on cement particle surfaces, and phosphonic-superplasticsizer has a stronger adsorption ability on silica fume particle surfaces. It is indicated that for a cement paste with the similar flow spread, a lower viscosity of the interstitial solutions is the main reason for a lower viscosity of paste with carboxylic-superplasticizer rather than that with phosphonic-superplasticsizer. However, the well- dispersion of silica fume particles with phosphonic-superplasticizer can result in an increased packing density, thus leading to a lower viscosity of cement-silica paste, compared to that of paste with carboxylic-superplasticizer.

, authors=Qianqian ZHANG1, Xin SHU1, Yong YANG1, Qianping RAN1, 2, authorsList=Qianqian ZHANG, Xin SHU, Yong YANG, Qianping RAN, authorCompany=null, correspAuthors=null, authorNote=

ZHANG Qianqian (1986—), female, Master, Senior Engineer. E-mail:

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为提升超高性能混凝土(UHPC)的工作性能,研究了两类减水剂对低水胶比水泥-硅灰浆体流变性能的影响,并通过分析减水剂的吸附行为、浆体中颗粒堆积密实度以及间隙液黏度等,揭示减水剂的吸附行为对UHPC浆体黏度的影响机制。结果表明:减水剂在不同粉体表面具有显著的选择性吸附行为,羧酸基减水剂对水泥具有优异的吸附能力,膦酸基减水剂对硅灰吸附能力更强;对于流动度相近的纯水泥浆体,低间隙液黏度是导致掺入羧酸基减水剂浆体黏度更低的主要原因;而膦酸基减水剂对硅灰更强的分散能力导致了水泥-硅灰浆体中颗粒堆积密实度大幅度增加,浆体黏度显著低于掺羧酸基减水剂的浆体。

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张倩倩(1986—),女,硕士,高级工程师。

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减水剂吸附行为对水泥-硅灰浆体黏度的影响
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张倩倩 1 , 舒鑫 1 , 杨勇 1 , 冉千平 1, 2
硅酸盐学报 | 超高性能混凝土专题Ⅱ 2020,48(11): 1716-1721
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硅酸盐学报 |超高性能混凝土专题Ⅱ 2020 , 48 (11) : 1716 -1721
减水剂吸附行为对水泥-硅灰浆体黏度的影响
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张倩倩1 , 舒鑫1, 杨勇1, 冉千平1, 2
作者信息
  • 1.高性能土木工程材料国家重点实验室,江苏苏博特新材料股份有限公司,南京 211103
  • 2.东南大学材料科学与工程学院,南京 211189
作者简介:

张倩倩(1986—),女,硕士,高级工程师。

Adsorption of Superplasticizer and its Effect on Viscosity of Cement-Silica Fume Paste
Qianqian ZHANG1 , Xin SHU1, Yong YANG1, Qianping RAN1, 2
Affiliations
  • 1.State Key Laboratory of High-Performance Civil Engineering Materials, Jiangsu Sobute New Materials Co., Ltd., Nanjing 210008, China
  • 2.School of Materials Science and Engineering, Southeast University, Nanjing 210096, China
  • ZHANG Qianqian (1986—), female, Master, Senior Engineer. E-mail:

出版时间: 2020-11-20 doi: 10.14062/j.issn.0454-5648.20200237
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为提升超高性能混凝土(UHPC)的工作性能,研究了两类减水剂对低水胶比水泥-硅灰浆体流变性能的影响,并通过分析减水剂的吸附行为、浆体中颗粒堆积密实度以及间隙液黏度等,揭示减水剂的吸附行为对UHPC浆体黏度的影响机制。结果表明:减水剂在不同粉体表面具有显著的选择性吸附行为,羧酸基减水剂对水泥具有优异的吸附能力,膦酸基减水剂对硅灰吸附能力更强;对于流动度相近的纯水泥浆体,低间隙液黏度是导致掺入羧酸基减水剂浆体黏度更低的主要原因;而膦酸基减水剂对硅灰更强的分散能力导致了水泥-硅灰浆体中颗粒堆积密实度大幅度增加,浆体黏度显著低于掺羧酸基减水剂的浆体。

超高性能混凝土  /  硅灰  /  减水剂  /  选择性吸附  /  颗粒堆积  /  间隙液黏度

To improve the workability of ultra-high performance concrete (UHPC), the effect of superplasticizers (i.e., carboxylic-superplasticizer and phosphonic-superplasticsizer) on the rheological properties of cement/silica fume pastes with a low water-binder ratio was investigated, and the adsorption behavior of the superplasticizers in paste, the packing density and the viscosity of interstitial solution were analyzed. The results show that the superplasticizers have a preferential adsorption behavior on different particle surfaces, and carboxylic-superplasticizer has a superior adsorption ability on cement particle surfaces, and phosphonic-superplasticsizer has a stronger adsorption ability on silica fume particle surfaces. It is indicated that for a cement paste with the similar flow spread, a lower viscosity of the interstitial solutions is the main reason for a lower viscosity of paste with carboxylic-superplasticizer rather than that with phosphonic-superplasticsizer. However, the well- dispersion of silica fume particles with phosphonic-superplasticizer can result in an increased packing density, thus leading to a lower viscosity of cement-silica paste, compared to that of paste with carboxylic-superplasticizer.

ultra-high performance concrete  /  silica fume  /  superplasticizer  /  preferential adsorption  /  packing density  /  viscosity of the interstitial solution
张倩倩, 舒鑫, 杨勇, 冉千平. 减水剂吸附行为对水泥-硅灰浆体黏度的影响. 硅酸盐学报, 2020 , 48 (11) : 1716 -1721 . DOI: 10.14062/j.issn.0454-5648.20200237
Qianqian ZHANG, Xin SHU, Yong YANG, Qianping RAN. Adsorption of Superplasticizer and its Effect on Viscosity of Cement-Silica Fume Paste[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (11) : 1716 -1721 . DOI: 10.14062/j.issn.0454-5648.20200237
  • 国家重点研发计划项目(2018YFC0705400)
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2020年第48卷第11期
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doi: 10.14062/j.issn.0454-5648.20200237
  • 接收时间:2020-03-31
  • 首发时间:2026-10-29
  • 出版时间:2020-11-20
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  • 收稿日期:2020-03-31
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国家重点研发计划项目(2018YFC0705400)
作者信息
    1.高性能土木工程材料国家重点实验室,江苏苏博特新材料股份有限公司,南京 211103
    2.东南大学材料科学与工程学院,南京 211189
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2种不同金属材料的力学参数
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属数
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genus
种数
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species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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