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Article(id=1322636257352594032, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636234858550134, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200148, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1583683200000, receivedDateStr=2020-03-09, revisedDate=1586620800000, revisedDateStr=2020-04-12, acceptedDate=null, acceptedDateStr=null, onlineDate=1793270657145, onlineDateStr=2026-10-29, pubDate=1603123200000, pubDateStr=2020-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793270657145, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793270657145, creator=13701087609, updateTime=1793270657145, updator=13701087609, issue=Issue{id=1322636234858550134, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='10', pageStart='1505', pageEnd='1688', issueExtLink='null', onlineDate='null', pubDate='1603123200000', pubDateStr='2020-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793270651783, creator='13701087609', updateTime=1793277146795, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663476976267430, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636234858550134, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663476976267431, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636234858550134, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1567, endPage=1573, ext={EN=ArticleExt(id=1322636257511977585, articleId=1322636257352594032, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Optical/Electrical Properties of Monoclinic Vanadium Dioxide Composite Film Embedded with Ag Nanoparticle Arrays, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Based on the hexagonal-close-packed polystyrene (PS) template, a monoclinic vanadium dioxide composite film (Ag NPAs/VO2(M)) embedded with Ag nanoparticle arrays was prepared on a quartz substrate via electronic beam evaporation. The microstructure, phase transition characteristics and light transmittance of composite film were investigated. The results show that VO2(M) and Ag phases both coexist in the composite film. The phase transition temperature of the composite film is as low as 55 ℃. Based on the analysis by the band model, the embedding of Ag nanoparticles increases the free electron concentration in the composite film and induces the phase transition to occur at a lower temperature. Compared to pure VO2 film, the transmittance of the composite film in the 590-750 nm band is weakened, which is attributed to the visible absorption of visible light in the 590-750 nm band by Ag NPAs in the composite film, thus weakening the inherent brownish yellow of the VO2 film.

, authors=Zhangyang ZHOU1, 2, Zhengwei XIONG2, Linhong CAO2, Weidong WU1, authorsList=Zhangyang ZHOU, Zhengwei XIONG, Linhong CAO, Weidong WU, authorCompany=null, correspAuthors=Zhengwei XIONG, Weidong WU, authorNote=

ZHOU Zhangyang (1995-), male, Master candidate. E-mail:

, correspAuthorsNote=
WU Weidong (1969-), male, Ph.D., Professor. E-mail:
XIONG Zhengwei (1984-), male, Ph. D., Associate Professor.
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基于六角密排聚苯乙烯（PS）模板，采用电子束蒸镀法在石英基片上制备了Ag纳米阵列嵌埋的单斜相二氧化钒复合薄膜（Ag NPAs/VO2（M）），研究复合薄膜的微观结构、相变特性及光透过率。结果表明：复合薄膜中同时存在VO2（M）和Ag两相。复合薄膜相变温度（TC）低至55 ℃，通过能带模型分析揭示了Ag纳米颗粒的嵌入使得复合薄膜中自由电子浓度升高，诱发相变在较低温度处发生。相对于纯的VO2薄膜，在590~750 nm波段的透射率明显减弱，归因于复合薄膜中Ag NPAs对590~750 nm波段的可见光共振吸收，使得VO2薄膜固有的棕黄色被削弱。

, authors=周章洋1, 2, 熊政伟2, 曹林洪2, 吴卫东1, authorsList=周章洋, 熊政伟, 曹林洪, 吴卫东, authorCompany=null, correspAuthors=熊政伟, 吴卫东, authorNote=

周章洋（1995—），男，硕士研究生。

, correspAuthorsNote=
吴卫东（1969—），男，博士，教授；
熊政伟（1984—），男，博士，副教授。
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ZHOU Zhangyang (1995-), male, Master candidate. E-mail:

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ZHOU Zhangyang (1995-), male, Master candidate. E-mail:

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周章洋（1995—），男，硕士研究生。

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周章洋（1995—），男，硕士研究生。

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Ag纳米阵列嵌埋单斜相二氧化钒复合薄膜的制备及光/电性能
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周章洋 1, 2 , 熊政伟 2 , 曹林洪 2 , 吴卫东 1
硅酸盐学报 | 2020,48(10): 1567-1573
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硅酸盐学报 | 2020 , 48 (10) : 1567 -1573
Ag纳米阵列嵌埋单斜相二氧化钒复合薄膜的制备及光/电性能
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周章洋1, 2 , 熊政伟2 , 曹林洪2, 吴卫东1
作者信息
  • 1．中国工程物理研究院激光聚变研究中心，四川 绵阳 621900
  • 2．西南科技大学，四川 绵阳 621900
通讯作者:
吴卫东（1969—），男，博士，教授；
熊政伟（1984—），男，博士，副教授。
作者简介:

周章洋（1995—），男，硕士研究生。

Optical/Electrical Properties of Monoclinic Vanadium Dioxide Composite Film Embedded with Ag Nanoparticle Arrays
Zhangyang ZHOU1, 2 , Zhengwei XIONG2 , Linhong CAO2, Weidong WU1
Affiliations
  • 1.Laser Fusion Research Center, China Academy of Engineering Physics, Mianyang 621900, Sichuan, China
  • 2.Southwest University of Science and Technology, Mianyang 621900, Sichuan, China
    • Corresponding Author:
    WU Weidong (1969-), male, Ph.D., Professor. E-mail:
    XIONG Zhengwei (1984-), male, Ph. D., Associate Professor.

    ZHOU Zhangyang (1995-), male, Master candidate. E-mail:

出版时间: 2020-10-20 doi: 10.14062/j.issn.0454-5648.20200148
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基于六角密排聚苯乙烯（PS）模板，采用电子束蒸镀法在石英基片上制备了Ag纳米阵列嵌埋的单斜相二氧化钒复合薄膜（Ag NPAs/VO2（M）），研究复合薄膜的微观结构、相变特性及光透过率。结果表明：复合薄膜中同时存在VO2（M）和Ag两相。复合薄膜相变温度（TC）低至55 ℃，通过能带模型分析揭示了Ag纳米颗粒的嵌入使得复合薄膜中自由电子浓度升高，诱发相变在较低温度处发生。相对于纯的VO2薄膜，在590~750 nm波段的透射率明显减弱，归因于复合薄膜中Ag NPAs对590~750 nm波段的可见光共振吸收，使得VO2薄膜固有的棕黄色被削弱。

二氧化钒  /  相变  /  透过率  /  银纳米颗粒

Based on the hexagonal-close-packed polystyrene (PS) template, a monoclinic vanadium dioxide composite film (Ag NPAs/VO2(M)) embedded with Ag nanoparticle arrays was prepared on a quartz substrate via electronic beam evaporation. The microstructure, phase transition characteristics and light transmittance of composite film were investigated. The results show that VO2(M) and Ag phases both coexist in the composite film. The phase transition temperature of the composite film is as low as 55 ℃. Based on the analysis by the band model, the embedding of Ag nanoparticles increases the free electron concentration in the composite film and induces the phase transition to occur at a lower temperature. Compared to pure VO2 film, the transmittance of the composite film in the 590-750 nm band is weakened, which is attributed to the visible absorption of visible light in the 590-750 nm band by Ag NPAs in the composite film, thus weakening the inherent brownish yellow of the VO2 film.

vanadium dioxide  /  phase transition  /  transmittance  /  silver nanoparticle arrays
周章洋, 熊政伟, 曹林洪, 吴卫东. Ag纳米阵列嵌埋单斜相二氧化钒复合薄膜的制备及光/电性能. 硅酸盐学报, 2020 , 48 (10) : 1567 -1573 . DOI: 10.14062/j.issn.0454-5648.20200148
Zhangyang ZHOU, Zhengwei XIONG, Linhong CAO, Weidong WU. Optical/Electrical Properties of Monoclinic Vanadium Dioxide Composite Film Embedded with Ag Nanoparticle Arrays[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (10) : 1567 -1573 . DOI: 10.14062/j.issn.0454-5648.20200148
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  • 国家自然科学基金(11904299)
  • 西南科技大学研究生创新基金(19ycx0066)
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2020年第48卷第10期
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doi: 10.14062/j.issn.0454-5648.20200148
  • 接收时间：2020-03-09
  • 首发时间：2026-10-29
  • 出版时间：2020-10-20
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  • 收稿日期：2020-03-09
  • 修回日期：2020-04-12
基金
国家自然科学基金(11904299)
西南科技大学研究生创新基金(19ycx0066)
作者信息
    1．中国工程物理研究院激光聚变研究中心，四川 绵阳 621900
    2．西南科技大学，四川 绵阳 621900

通讯作者:

吴卫东（1969—），男，博士，教授；
熊政伟（1984—），男，博士，副教授。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20200148
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2种不同金属材料的力学参数
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Number of
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Percentage of
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Genus		 种数
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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