Article(id=1322622778126217725, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200065, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1581264000000, receivedDateStr=2020-02-10, revisedDate=1582732800000, revisedDateStr=2020-02-27, acceptedDate=null, acceptedDateStr=null, onlineDate=1793267443447, onlineDateStr=2026-10-29, pubDate=1595174400000, pubDateStr=2020-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793267443447, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793267443447, creator=13701087609, updateTime=1793267443447, updator=13701087609, issue=Issue{id=1322622757339250965, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='7', pageStart='939', pageEnd='1144', issueExtLink='null', onlineDate='null', pubDate='1595174400000', pubDateStr='2020-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793267438492, creator='13701087609', updateTime=1793277091258, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663244053992200, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663244053992201, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1055, endPage=1061, ext={EN=ArticleExt(id=1322622779464200702, articleId=1322622778126217725, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Lithium Metal Anode Modified by Lithium Acetate In Situ and Its Cycling Stability, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Surface modification and protection of lithium metal are widely regarded as effective methods to improve lithium deposition behaviors as well as suppress lithium dendrites. In this paper, acetic acid gas was used to react with lithium metal to obtain CH₃COOLi-Li anode. A lithium acetate passivation film formed on the lithium surface could prevent lithium metal from further reacting with the electrolyte, thus inhibiting lithium dendrite growth during cycling. The lithium battery, lithium copper battery, and lithium cobaltate full battery were assembled for electrochemical characterization of a proposed modified metal anode. The results show that CH₃COOLi-Li anode has a better cycle stability performance than pure Li anode. The Coulomb efficiency of lithium copper battery with CH₃COOLi-Li anode after 100 cycles remains at 97%, and CH₃COOLi-Li/LiCoO₂ full battery has a capacity retention rate of 73.5% after 1 000 cycles.

, authors=Yuqi CHEN¹, Qiang ZHAO¹, Yuchuan FENG², Hongcai HE^{1, 2}, authorsList=Yuqi CHEN, Qiang ZHAO, Yuchuan FENG, Hongcai HE, authorCompany=null, correspAuthors=Hongcai HE, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322622779908796927, articleId=1322622778126217725, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=原位生成醋酸锂改性金属锂负极及其稳定性, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

为了提高锂负极的循环稳定性能，需要对金属锂进行改性保护，改善锂沉积行为，抑制锂枝晶的产生。主要使用冰醋酸挥发气体与锂负极原位反应，在金属锂表面原位形成一层醋酸锂，得到CH₃COOLi-Li负极。表面形成的醋酸锂钝化膜可以抑制锂与电解液的反应，抑制循环过程中锂枝晶的生长。组装对称锂电池、锂铜电池和钴酸锂全电池并对其进行电化学表征，均表明CH₃COOLi-Li负极相比于纯Li负极，电池的循环稳定性能得到明显改善。CH₃COOLi-Li负极的锂铜电池循环100圈后Coulomb效率仍稳定在97%以上，组装的CH₃COOLi-Li/LiCoO₂全电池循环1 000圈容量保持率高达73.5%。

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CHEN Yuqi (1995-), male, Master candidate. E-mail: cyq15882243245@163.com

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CHEN Yuqi (1995-), male, Master candidate. E-mail: cyq15882243245@163.com

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陈昱锜（1995—），男，硕士研究生。

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陈昱锜（1995—），男，硕士研究生。

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