Article(id=1322622769708253557, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200060, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1581264000000, receivedDateStr=2020-02-10, revisedDate=1581868800000, revisedDateStr=2020-02-17, acceptedDate=null, acceptedDateStr=null, onlineDate=1793267441440, onlineDateStr=2026-10-29, pubDate=1595174400000, pubDateStr=2020-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793267441440, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793267441440, creator=13701087609, updateTime=1793267441440, updator=13701087609, issue=Issue{id=1322622757339250965, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='7', pageStart='939', pageEnd='1144', issueExtLink='null', onlineDate='null', pubDate='1595174400000', pubDateStr='2020-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793267438492, creator='13701087609', updateTime=1793277091258, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663244053992200, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663244053992201, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1025, endPage=1033, ext={EN=ArticleExt(id=1322622769938940278, articleId=1322622769708253557, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Research Progress of Inorganic Cathode Materials for Potassium-ion Batteries, columnId=1322622757976785174, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on New-type Battery, runingTitle=null, highlight=null, articleAbstract=

Potassium ion is heavier and larger than lithium ion, having some features such as harder to diffuse in electrode materials and causing a greater structural stress in electrode material during charging and discharging, thus resulting in the collapse of the electrode. The development of potassium ion battery, especially to the advancement of its cathode material becomes thus a challenge. In order to tackle these problems, some work are carried out in the field of potassium ion battery, and the corresponding results show that cathode materials (i.e., layered metal oxides, polyanionic-type material, Prussian blue and its derivatives) exhibit better potassium storage properties. This review represented various cathode materials used for potassium ion battery and recent developments, mainly including the potassium storage mechanism, electrochemical performance, existing problems and potential strategies. In addition, some possible future research aspects for the cathode material in potassium ion batteries were also addressed.

, authors=Xianghua ZHANG1, Wei LUO1, Xianhong RUI1, Yan YU2, authorsList=Xianghua ZHANG, Wei LUO, Xianhong RUI, Yan YU, authorCompany=null, correspAuthors=Xianhong RUI, Yan YU, authorNote=

ZHANG Xianghua (1992-), female, Ph.D. candidate. E-mail:

, correspAuthorsNote=
RUI Xianhong (1985-), male, Ph.D., Professor; E-mail:
YU Yan (1979-), female, Ph.D., Professor.
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钾离子与锂离子相比,钾离子的质量重且离子半径大,使其在电极材料中的扩散较困难并会产生较大的结构应力造成电极坍塌,这给钾离子电池的研发带来了极大的挑战,尤其是正极材料。针对这些问题,研究者们做了大量的探索工作,其中层状金属氧化物、聚阴离子型化合物、普鲁士蓝及其类似物等正极材料展现出了较好的储钾性能。因此,详细概述了这些正极材料的最新研究进展,主要包括钾离子的脱嵌机理、电化学性能、存在的问题和改性策略。最后,对钾离子电池正极材料的未来研究方向作出展望。

, authors=张香华1, 骆微1, 芮先宏1, 余彦2, authorsList=张香华, 骆微, 芮先宏, 余彦, authorCompany=null, correspAuthors=芮先宏, 余彦, authorNote=

张香华(1992—),女,博士研究生。

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芮先宏(1985—),男,博士,教授;
余彦(1979—),女,博士,教授。
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钾离子电池无机正极材料的研究进展
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张香华 1 , 骆微 1 , 芮先宏 1 , 余彦 2
硅酸盐学报 | 新型电池专题—综合评述 2020,48(7): 1025-1033
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硅酸盐学报 |新型电池专题—综合评述 2020 , 48 (7) : 1025 -1033
钾离子电池无机正极材料的研究进展
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张香华1 , 骆微1, 芮先宏1 , 余彦2
作者信息
  • 1.广东工业大学材料与能源学院,广州 510080
  • 2.中国科学技术大学材料科学与工程系,合肥 230026
通讯作者:
芮先宏(1985—),男,博士,教授;
余彦(1979—),女,博士,教授。
作者简介:

张香华(1992—),女,博士研究生。

Research Progress of Inorganic Cathode Materials for Potassium-ion Batteries
Xianghua ZHANG1 , Wei LUO1, Xianhong RUI1 , Yan YU2
Affiliations
  • 1.School of Materials and Energy, Guangdong University of Technology, Guangzhou 510080, China
  • 2.Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China
  • Corresponding Author:
    RUI Xianhong (1985-), male, Ph.D., Professor; E-mail:
    YU Yan (1979-), female, Ph.D., Professor.

    ZHANG Xianghua (1992-), female, Ph.D. candidate. E-mail:

出版时间: 2020-07-20 doi: 10.14062/j.issn.0454-5648.20200060
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钾离子与锂离子相比,钾离子的质量重且离子半径大,使其在电极材料中的扩散较困难并会产生较大的结构应力造成电极坍塌,这给钾离子电池的研发带来了极大的挑战,尤其是正极材料。针对这些问题,研究者们做了大量的探索工作,其中层状金属氧化物、聚阴离子型化合物、普鲁士蓝及其类似物等正极材料展现出了较好的储钾性能。因此,详细概述了这些正极材料的最新研究进展,主要包括钾离子的脱嵌机理、电化学性能、存在的问题和改性策略。最后,对钾离子电池正极材料的未来研究方向作出展望。

钾离子电池  /  正极材料  /  层状金属氧化物  /  聚阴离子化合物  /  普鲁士蓝及其类似物

Potassium ion is heavier and larger than lithium ion, having some features such as harder to diffuse in electrode materials and causing a greater structural stress in electrode material during charging and discharging, thus resulting in the collapse of the electrode. The development of potassium ion battery, especially to the advancement of its cathode material becomes thus a challenge. In order to tackle these problems, some work are carried out in the field of potassium ion battery, and the corresponding results show that cathode materials (i.e., layered metal oxides, polyanionic-type material, Prussian blue and its derivatives) exhibit better potassium storage properties. This review represented various cathode materials used for potassium ion battery and recent developments, mainly including the potassium storage mechanism, electrochemical performance, existing problems and potential strategies. In addition, some possible future research aspects for the cathode material in potassium ion batteries were also addressed.

potassium ion batteries  /  cathode materials  /  layered metal oxides  /  polyanion compounds  /  Prussian blue analogues
张香华, 骆微, 芮先宏, 余彦. 钾离子电池无机正极材料的研究进展. 硅酸盐学报, 2020 , 48 (7) : 1025 -1033 . DOI: 10.14062/j.issn.0454-5648.20200060
Xianghua ZHANG, Wei LUO, Xianhong RUI, Yan YU. Research Progress of Inorganic Cathode Materials for Potassium-ion Batteries[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (7) : 1025 -1033 . DOI: 10.14062/j.issn.0454-5648.20200060
  • 国家自然科学基金(51972067; 51925207; U1910210)
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2020年第48卷第7期
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doi: 10.14062/j.issn.0454-5648.20200060
  • 接收时间:2020-02-10
  • 首发时间:2026-10-29
  • 出版时间:2020-07-20
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  • 收稿日期:2020-02-10
  • 修回日期:2020-02-17
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国家自然科学基金(51972067; 51925207; U1910210)
作者信息
    1.广东工业大学材料与能源学院,广州 510080
    2.中国科学技术大学材料科学与工程系,合肥 230026

通讯作者:

芮先宏(1985—),男,博士,教授;
余彦(1979—),女,博士,教授。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20200060
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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