Article(id=1322622784317018681, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200041, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1579449600000, receivedDateStr=2020-01-20, revisedDate=1582473600000, revisedDateStr=2020-02-24, acceptedDate=null, acceptedDateStr=null, onlineDate=1793267444923, onlineDateStr=2026-10-29, pubDate=1595174400000, pubDateStr=2020-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793267444923, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793267444923, creator=13701087609, updateTime=1793267444923, updator=13701087609, issue=Issue{id=1322622757339250965, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='7', pageStart='939', pageEnd='1144', issueExtLink='null', onlineDate='null', pubDate='1595174400000', pubDateStr='2020-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793267438492, creator='13701087609', updateTime=1793277091258, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663244053992200, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663244053992201, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=978, endPage=989, ext={EN=ArticleExt(id=1322622784979718714, articleId=1322622784317018681, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Kinetics Activated Magnesium Metal Batteries Based on Conversion Reaction, columnId=1322622757976785174, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on New-type Battery, runingTitle=null, highlight=null, articleAbstract=

Compared to magnesium metal batteries (MMBs) based on pure Mg²⁺ electrolyte, the MMBs based on hybrid electrolyte containing Mg²⁺ and Li⁺ possess some advantages such as long cycle life, fast charge and discharge processes, high Coulomb efficiency and more choices of cathode materials. The energy density of MMBs can be improved especially when conversion-based cathode materials are used. Recent development on dual-salt magnesium batteries based on conversion reaction or multiple electron transfer process was reviewed based on the aspects of sulfide and organic cathode materials. With the assistance of nano-structure regulation, conductive network construction, and ion pillaring, Mg-S and Mg-rhodizonate batteries are able to achieve a high energy density (i.e., 500 W·h/kg based on active cathode material) and a long-term cycle stability. This review proposed an additive salt strategy to accelerate the kinetics of MMBs based on conversion reaction, and provided some fresh insights for the future development of magnesium-based batteries.

, authors=Wenlong LIU^{1, 2}, Kexian HUANG¹, Xuejun ZHOU¹, Chilin LI^{1, 2}, authorsList=Wenlong LIU, Kexian HUANG, Xuejun ZHOU, Chilin LI, authorCompany=null, correspAuthors=Chilin LI, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322622785332040251, articleId=1322622784317018681, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=动力学激活的转换型镁金属电池, columnId=1322622758136168728, journalTitle=硅酸盐学报, columnName=新型电池专题—综合评述, runingTitle=null, highlight=null, articleAbstract=

对比纯镁电解液的镁电池，锂镁双盐混合电池具有循环寿命长、充放电速度快、Coulomb效率高、正极选择多等特点，特别当采用容量更高的转换反应型正极时，可显著提高镁电池的能量密度。从硫基和有机正极材料方面综述了转换反应型或多电子转移型双盐电池的研究进展，通过纳米结构调控、导电网络构筑、支撑离子诱导等手段，实现了镁硫电池和镁玫瑰酸盐电池的能量密度提升和长期循环稳定，它们的正极能量密度可达500 W·h/kg。提出了添加剂盐激活转换型镁金属电池的策略，为未来镁基电池的发展提供了新的思路。

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