Article(id=1322636250348106311, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636234858550134, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200007, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1578240000000, receivedDateStr=2020-01-06, revisedDate=1584979200000, revisedDateStr=2020-03-24, acceptedDate=null, acceptedDateStr=null, onlineDate=1793270655476, onlineDateStr=2026-10-29, pubDate=1603123200000, pubDateStr=2020-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793270655476, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793270655476, creator=13701087609, updateTime=1793270655476, updator=13701087609, issue=Issue{id=1322636234858550134, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='10', pageStart='1505', pageEnd='1688', issueExtLink='null', onlineDate='null', pubDate='1603123200000', pubDateStr='2020-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793270651783, creator='13701087609', updateTime=1793277146795, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663476976267430, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636234858550134, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663476976267431, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636234858550134, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1559, endPage=1566, ext={EN=ArticleExt(id=1322636251954524744, articleId=1322636250348106311, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Surface Modification of TiO2 Nanosheet Array and Its Application in Hybrid Solar Cells, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

TiO2 nanosheets (TNS) were prepared on fluorine-doped tin oxide (FTO) glass via hydrothermal reaction, and triphenylamine complex D2 was used to modify the TNS array. The microstructure and photoelectric conversion performance of hybrid solar cells were characterized by scanning electronic microscopy, X-ray diffraction, ultraviolet-visible spectroscopy, transient photocurrent spectroscopy, photoluminnescence spectroscopy, contact angle measurement, current density-voltage (J-V) test, and electrochemical impedance spectroscopy. The results show that triphenylamine complex D2 improves the chemical compatibility between organic polymers and inorganic materials. According to the results by contact angle measurement, the surface of TiO2 particles changes from hydrophilic to hydrophobic after modification. The results by electrochemical impedance spectroscopy indicate that the recombination resistance and electronic lifetime of the cell device after modified on the surface of TiO2 particles increase from 866.8 Ω·cm2 and 48.1 μs to 932.2 Ω·cm2 and 127.1 μs, respectively. In the TNS-based hybrid solar cell, the photoelectric conversion efficiency of the modified cell improves from 0.20% to 1.52%, compared to that of the unmodified device.

, authors=Xue ZHAO, Juan PEI, Xueting HUANG, Yanzhong HAO, authorsList=Xue ZHAO, Juan PEI, Xueting HUANG, Yanzhong HAO, authorCompany=null, correspAuthors=Juan PEI, authorNote=

ZHAO Xue (1995-), female, Master candidate. E-mail:

, correspAuthorsNote=
PEI Juan (1981-), female, Ph.D., Professor. E-mail:
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通过水热法在氟掺杂氧化锡导电玻璃(FTO glass)上成功制备出TiO2纳米片(TNS)阵列。使用三苯胺配合物D2对FTO/TNS进行表面改性处理,并使用扫描电子显微镜、X射线衍射仪、紫外可见吸收光谱、瞬态光电流、荧光光谱、接触角、电流密度-电压(J-V)测试仪、电化学阻抗谱对电极的结构形貌、表面特性以及电池的光电特性进行了表征,发现表面改性可提高有机聚合物与无机材料之间的化学相容性。接触角测试表明:TiO2表面改性后由亲水性向疏水性转变。电化学阻抗分析表明:TiO2表面改性后界面的复合电阻和电子寿命分别由原来的866.8 Ω·cm2和48.1 μs增大至932.2 Ω·cm2和127.1 μs。J-V曲线表明:与未改性的电池相比,改性后电池的光电转换效率由未改性的0.20%提高到1.52%。

, authors=赵雪, 裴娟, 黄雪婷, 郝彦忠, authorsList=赵雪, 裴娟, 黄雪婷, 郝彦忠, authorCompany=null, correspAuthors=裴娟, authorNote=

赵雪(1995—),女,硕士研究生。

, correspAuthorsNote=
裴娟(1981—),女,博士,教授。
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TiO2纳米片阵列的表面改性及其在杂化太阳能电池中的应用
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赵雪 , 裴娟 , 黄雪婷 , 郝彦忠
硅酸盐学报 | 2020,48(10): 1559-1566
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硅酸盐学报 | 2020 , 48 (10) : 1559 -1566
TiO2纳米片阵列的表面改性及其在杂化太阳能电池中的应用
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赵雪 , 裴娟 , 黄雪婷, 郝彦忠
作者信息
  • 河北科技大学理学院,石家庄 050018
通讯作者:
裴娟(1981—),女,博士,教授。
作者简介:

赵雪(1995—),女,硕士研究生。

Surface Modification of TiO2 Nanosheet Array and Its Application in Hybrid Solar Cells
Xue ZHAO , Juan PEI , Xueting HUANG, Yanzhong HAO
Affiliations
  • College of Sciences, Hebei University of Science and Technology, Shijiazhuang 050018, China
  • Corresponding Author:
    PEI Juan (1981-), female, Ph.D., Professor. E-mail:

    ZHAO Xue (1995-), female, Master candidate. E-mail:

出版时间: 2020-10-20 doi: 10.14062/j.issn.0454-5648.20200007
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通过水热法在氟掺杂氧化锡导电玻璃(FTO glass)上成功制备出TiO2纳米片(TNS)阵列。使用三苯胺配合物D2对FTO/TNS进行表面改性处理,并使用扫描电子显微镜、X射线衍射仪、紫外可见吸收光谱、瞬态光电流、荧光光谱、接触角、电流密度-电压(J-V)测试仪、电化学阻抗谱对电极的结构形貌、表面特性以及电池的光电特性进行了表征,发现表面改性可提高有机聚合物与无机材料之间的化学相容性。接触角测试表明:TiO2表面改性后由亲水性向疏水性转变。电化学阻抗分析表明:TiO2表面改性后界面的复合电阻和电子寿命分别由原来的866.8 Ω·cm2和48.1 μs增大至932.2 Ω·cm2和127.1 μs。J-V曲线表明:与未改性的电池相比,改性后电池的光电转换效率由未改性的0.20%提高到1.52%。

二氧化钛纳米片  /  表面改性  /  杂化太阳能电池  /  光电转换效率

TiO2 nanosheets (TNS) were prepared on fluorine-doped tin oxide (FTO) glass via hydrothermal reaction, and triphenylamine complex D2 was used to modify the TNS array. The microstructure and photoelectric conversion performance of hybrid solar cells were characterized by scanning electronic microscopy, X-ray diffraction, ultraviolet-visible spectroscopy, transient photocurrent spectroscopy, photoluminnescence spectroscopy, contact angle measurement, current density-voltage (J-V) test, and electrochemical impedance spectroscopy. The results show that triphenylamine complex D2 improves the chemical compatibility between organic polymers and inorganic materials. According to the results by contact angle measurement, the surface of TiO2 particles changes from hydrophilic to hydrophobic after modification. The results by electrochemical impedance spectroscopy indicate that the recombination resistance and electronic lifetime of the cell device after modified on the surface of TiO2 particles increase from 866.8 Ω·cm2 and 48.1 μs to 932.2 Ω·cm2 and 127.1 μs, respectively. In the TNS-based hybrid solar cell, the photoelectric conversion efficiency of the modified cell improves from 0.20% to 1.52%, compared to that of the unmodified device.

titanium dioxide nanosheets  /  surface modification  /  hybrid solar cell  /  photoelectric conversion efficiency
赵雪, 裴娟, 黄雪婷, 郝彦忠. TiO2纳米片阵列的表面改性及其在杂化太阳能电池中的应用. 硅酸盐学报, 2020 , 48 (10) : 1559 -1566 . DOI: 10.14062/j.issn.0454-5648.20200007
Xue ZHAO, Juan PEI, Xueting HUANG, Yanzhong HAO. Surface Modification of TiO2 Nanosheet Array and Its Application in Hybrid Solar Cells[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (10) : 1559 -1566 . DOI: 10.14062/j.issn.0454-5648.20200007
  • 国家自然科学基金(21603053; 21173065)
  • 河北省自然科学基金(B2014208062; B2014208066)
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doi: 10.14062/j.issn.0454-5648.20200007
  • 接收时间:2020-01-06
  • 首发时间:2026-10-29
  • 出版时间:2020-10-20
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  • 收稿日期:2020-01-06
  • 修回日期:2020-03-24
基金
国家自然科学基金(21603053; 21173065)
河北省自然科学基金(B2014208062; B2014208066)
作者信息
    河北科技大学理学院,石家庄 050018

通讯作者:

裴娟(1981—),女,博士,教授。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20200007
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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