Article(id=1322622779850080710, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.2020.07.20190682, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1571155200000, receivedDateStr=2019-10-16, revisedDate=1579190400000, revisedDateStr=2020-01-17, acceptedDate=null, acceptedDateStr=null, onlineDate=1793267443858, onlineDateStr=2026-10-29, pubDate=1595174400000, pubDateStr=2020-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793267443858, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793267443858, creator=13701087609, updateTime=1793267443858, updator=13701087609, issue=Issue{id=1322622757339250965, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='7', pageStart='939', pageEnd='1144', issueExtLink='null', onlineDate='null', pubDate='1595174400000', pubDateStr='2020-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793267438492, creator='13701087609', updateTime=1793277091258, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663244053992200, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663244053992201, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1097, endPage=1106, ext={EN=ArticleExt(id=1322622780076573127, articleId=1322622779850080710, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Enhanced Photocatalytic Performance of α-Fe2O3 Modified Hollow Glass Microspheres/ZnIn2S4 Composite Photocatalyst, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

A floating composite photocatalyst of hollow glass microspheres (HGM)/ZnIn2S4/α-Fe2O3 was prepared by a modified hydrothermal method. The HGM/ZnIn2S4 composite was firstly prepared with HGM as a carrier, and then further modified with nanorod-shaped α-Fe2O3 to obtain the floating composite photocatalysts of HGM/ZnIn2S4/α-Fe2O3. The effects of α-Fe2O3 content, photocatalysts addition and solution pH value on the photocatalytic activity of the composite photocatalysts for the degradation of hexavalent chromium (Cr6+) were investigated. The results show that α-Fe2O3 and hexagonal ZnIn2S4 heterogeneous structure are formed, and the composite photocatalyst is uniformly loaded on the surface of HGM. Compared to α-Fe2O3 powder and HGM/ZnIn2S4 composite microspheres, the photocatalytic performance of HGM/ZnIn2S4/α-Fe2O3 is improved. The prepared composite photocatalyst still has a good photocatalytic efficiency after several recycling. In addition, the synthesis mechanism of HGM/ZnIn2S4/α-Fe2O3 and its enhanced photocatalytic mechanism were also discussed.

, authors=Xu HAN1, 2, 3, 4, Leilei WANG1, 2, 3, 4, Lei WANG1, 2, 3, 4, Xudong WANG1, 2, 3, 4, Deqiang ZHAO5, authorsList=Xu HAN, Leilei WANG, Lei WANG, Xudong WANG, Deqiang ZHAO, authorCompany=null, correspAuthors=Lei WANG, authorNote=

HAN Xu (1995-), female, Master candidate. E-mail:

, correspAuthorsNote=
WANG Lei (1971-), male, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322622780353397192, articleId=1322622779850080710, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=α-Fe2O3改性空心玻璃微球/ZnIn2S4复合催化剂的制备及增强型光催化性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

采用改良后的水热法制备空心玻璃微球(HGM)/ZnIn2S4/α-Fe2O3漂浮型复合光催化剂。以HGM为载体,首先制备HGM/ZnIn2S4复合微球,然后利用自制的纳米棒状α-Fe2O3进一步改性,得到HGM/ZnIn2S4/α-Fe2O3漂浮型复合光催化剂。以六价铬(Cr6+)为目标污染物,研究了α-Fe2O3含量、催化剂投加量和原液pH值对复合催化剂光催化活性的影响。结果表明:纳米棒状α-Fe2O3与六方相型ZnIn2S4形成异质结构并均匀负载在HGM表面,形成HGM/ZnIn2S4/α-Fe2O3复合光催化剂,与α-Fe2O3粉体和HGM/ZnIn2S4复合微球相比,HGM/ZnIn2S4/α-Fe2O3漂浮型复合光催化剂的催化性能显著提高,且再循环后仍具有良好的光催化效率,并提出了HGM/ZnIn2S4/α-Fe2O3的增强型光催化机制。

, authors=韩煦1, 2, 3, 4, 王雷磊1, 2, 3, 4, 王磊1, 2, 3, 4, 王旭东1, 2, 3, 4, 赵德强5, authorsList=韩煦, 王雷磊, 王磊, 王旭东, 赵德强, authorCompany=null, correspAuthors=王磊, authorNote=

韩煦(1995—),女,硕士研究生。

, correspAuthorsNote=
王磊(1971—),男,博士,教授。
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α-Fe2O3改性空心玻璃微球/ZnIn2S4复合催化剂的制备及增强型光催化性能
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韩煦 1, 2, 3, 4 , 王雷磊 1, 2, 3, 4 , 王磊 1, 2, 3, 4 , 王旭东 1, 2, 3, 4 , 赵德强 5
硅酸盐学报 | 研究论文 2020,48(7): 1097-1106
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硅酸盐学报 |研究论文 2020 , 48 (7) : 1097 -1106
α-Fe2O3改性空心玻璃微球/ZnIn2S4复合催化剂的制备及增强型光催化性能
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韩煦1, 2, 3, 4 , 王雷磊1, 2, 3, 4, 王磊1, 2, 3, 4 , 王旭东1, 2, 3, 4, 赵德强5
作者信息
  • 1.西安建筑科技大学环境与市政工程学院,西安 710055
  • 2.陕西省膜分离技术研究院,西安 710055
  • 3.陕西省膜分离重点实验室,西安 710055
  • 4.陕西省环境工程重点实验室,西安 710055
  • 5.重庆交通大学河海学院,城市水务与环境监测及控制实验室,重庆 400074
通讯作者:
王磊(1971—),男,博士,教授。
作者简介:

韩煦(1995—),女,硕士研究生。

Preparation and Enhanced Photocatalytic Performance of α-Fe2O3 Modified Hollow Glass Microspheres/ZnIn2S4 Composite Photocatalyst
Xu HAN1, 2, 3, 4 , Leilei WANG1, 2, 3, 4, Lei WANG1, 2, 3, 4 , Xudong WANG1, 2, 3, 4, Deqiang ZHAO5
Affiliations
  • 1.Xi'an University of Architecture and Technology, Department of Environmental and Municipal Engineering, Xi'an 710055, China
  • 2.Research Institute of Membrane Separation Technology of Shaanxi Province, Xi'an 710055, China
  • 3.Key Laboratory of Membrane Separation of Shaanxi Province, Xi'an 710055, China
  • 4.Shaanxi Key Laboratory of Environment Engineering, Xi'an 710055, China
  • 5.School of Rive and Ocean Engineering, Chongqing Jiaotong University, Laboratory of Urban Water and Environment Monitoring and Control, Chongqing 400074, China
  • Corresponding Author:
    WANG Lei (1971-), male, Ph.D., Professor. E-mail:

    HAN Xu (1995-), female, Master candidate. E-mail:

出版时间: 2020-07-20 doi: 10.14062/j.issn.0454-5648.2020.07.20190682
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采用改良后的水热法制备空心玻璃微球(HGM)/ZnIn2S4/α-Fe2O3漂浮型复合光催化剂。以HGM为载体,首先制备HGM/ZnIn2S4复合微球,然后利用自制的纳米棒状α-Fe2O3进一步改性,得到HGM/ZnIn2S4/α-Fe2O3漂浮型复合光催化剂。以六价铬(Cr6+)为目标污染物,研究了α-Fe2O3含量、催化剂投加量和原液pH值对复合催化剂光催化活性的影响。结果表明:纳米棒状α-Fe2O3与六方相型ZnIn2S4形成异质结构并均匀负载在HGM表面,形成HGM/ZnIn2S4/α-Fe2O3复合光催化剂,与α-Fe2O3粉体和HGM/ZnIn2S4复合微球相比,HGM/ZnIn2S4/α-Fe2O3漂浮型复合光催化剂的催化性能显著提高,且再循环后仍具有良好的光催化效率,并提出了HGM/ZnIn2S4/α-Fe2O3的增强型光催化机制。

水热法  /  α-三氧化二铁  /  硫铟锌  /  异质结  /  漂浮型负载  /  空心玻璃微球

A floating composite photocatalyst of hollow glass microspheres (HGM)/ZnIn2S4/α-Fe2O3 was prepared by a modified hydrothermal method. The HGM/ZnIn2S4 composite was firstly prepared with HGM as a carrier, and then further modified with nanorod-shaped α-Fe2O3 to obtain the floating composite photocatalysts of HGM/ZnIn2S4/α-Fe2O3. The effects of α-Fe2O3 content, photocatalysts addition and solution pH value on the photocatalytic activity of the composite photocatalysts for the degradation of hexavalent chromium (Cr6+) were investigated. The results show that α-Fe2O3 and hexagonal ZnIn2S4 heterogeneous structure are formed, and the composite photocatalyst is uniformly loaded on the surface of HGM. Compared to α-Fe2O3 powder and HGM/ZnIn2S4 composite microspheres, the photocatalytic performance of HGM/ZnIn2S4/α-Fe2O3 is improved. The prepared composite photocatalyst still has a good photocatalytic efficiency after several recycling. In addition, the synthesis mechanism of HGM/ZnIn2S4/α-Fe2O3 and its enhanced photocatalytic mechanism were also discussed.

hydrothermal method  /  α-iron oxide  /  indium sulfur zinc  /  heterojunction  /  floating load  /  hollow glass microsphere
韩煦, 王雷磊, 王磊, 王旭东, 赵德强. α-Fe2O3改性空心玻璃微球/ZnIn2S4复合催化剂的制备及增强型光催化性能. 硅酸盐学报, 2020 , 48 (7) : 1097 -1106 . DOI: 10.14062/j.issn.0454-5648.2020.07.20190682
Xu HAN, Leilei WANG, Lei WANG, Xudong WANG, Deqiang ZHAO. Preparation and Enhanced Photocatalytic Performance of α-Fe2O3 Modified Hollow Glass Microspheres/ZnIn2S4 Composite Photocatalyst[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (7) : 1097 -1106 . DOI: 10.14062/j.issn.0454-5648.2020.07.20190682
  • 陕西省重点科技创新团队计划(2017KCT-19-01)
  • 陕西省重点产业链(群)项目(2017ZDCXL-GY-07-03)
  • 陕西省技术创新引导专项(2018HJCG-18)
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2020年第48卷第7期
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doi: 10.14062/j.issn.0454-5648.2020.07.20190682
  • 接收时间:2019-10-16
  • 首发时间:2026-10-29
  • 出版时间:2020-07-20
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  • 收稿日期:2019-10-16
  • 修回日期:2020-01-17
基金
陕西省重点科技创新团队计划(2017KCT-19-01)
陕西省重点产业链(群)项目(2017ZDCXL-GY-07-03)
陕西省技术创新引导专项(2018HJCG-18)
作者信息
    1.西安建筑科技大学环境与市政工程学院,西安 710055
    2.陕西省膜分离技术研究院,西安 710055
    3.陕西省膜分离重点实验室,西安 710055
    4.陕西省环境工程重点实验室,西安 710055
    5.重庆交通大学河海学院,城市水务与环境监测及控制实验室,重庆 400074

通讯作者:

王磊(1971—),男,博士,教授。
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2种不同金属材料的力学参数
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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