Article(id=1322612349152899261, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612265061306700, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.2020.05.20190745, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1573401600000, receivedDateStr=2019-11-11, revisedDate=1575388800000, revisedDateStr=2019-12-04, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264956987, onlineDateStr=2026-10-29, pubDate=1589904000000, pubDateStr=2020-05-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264956987, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264956987, creator=13701087609, updateTime=1793264956987, updator=13701087609, issue=Issue{id=1322612265061306700, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='5', pageStart='615', pageEnd='786', issueExtLink='null', onlineDate='null', pubDate='1589904000000', pubDateStr='2020-05-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264936938, creator='13701087609', updateTime=1793276961694, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322662700602208333, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612265061306700, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322662700602208334, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612265061306700, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=718, endPage=722, ext={EN=ArticleExt(id=1322612349316477118, articleId=1322612349152899261, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Temperature Dependence of Viscosity and Fragility of Ge
10As
40Se
50 Chalcogenide Glass, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=
The viscosity of Ge10As40Se50 chalcogenide glass was investigated by fiber elongation and rotation methods. The Vogel-Fulcher-Tammann equation was proposed as an optimal fitting model after comparing to the accuracy of different equations. GexAsySe1-x-y glasses were compared according to the fragility, m, derived from the Angell plot. The network structure of Ge10As40Se50 chalcogenide glass was investigated by X-ray photoelectron spectroscopy (XPS). The results show that the fragility change of GexAsySe1-x-y glasses follows the topological constraint theory in the range of the average coordination numbers (i.e., r=2.0-2.6). The m of GexAsySe1-x-y glasses decreases as r increases. However, the m does not strictly decrease as r increases when r is greater than 2.2. Based on the XPS results, Ge10As40Se50 chalcogenide glass exists Se chain in the network structure, thus affecting the stability and results at a greater m.
, authors=Peng ZHOU
1, Hua ZHAO
1, Chengkui ZU
1, Tengxiao GUO
2, Jianjie XU
2, Yonghua LIU
1, Haizheng TAO
3, Kaiwen SHI
3, Rui ZHANG
1, Wei CHEN
1, authorsList=Peng ZHOU, Hua ZHAO, Chengkui ZU, Tengxiao GUO, Jianjie XU, Yonghua LIU, Haizheng TAO, Kaiwen SHI, Rui ZHANG, Wei CHEN, authorCompany=null, correspAuthors=Chengkui ZU, authorNote=
, correspAuthorsNote=
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322612349937234111, articleId=1322612349152899261, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=Ge
10As
40Se
50硫系玻璃黏温性能及动力学强弱性, columnId=null, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=
采用纤维伸长法、旋转法测试了Ge10As40Se50硫系玻璃的黏度。通过比较不同方程的准确性,确定Vogel-Fulcher-Tammann方程为该玻璃黏度拟合的最优模型,推导出玻璃黏度随温度的变化关系,根据Angell图计算其强弱性指数m,与其他GexAsySe1-x-y玻璃的m进行比较,采用X射线光电子能谱仪对其网络结构进行分析。结果表明:在平均配位数r为2.0~2.6区间内,GexAsySe1-x-y系统玻璃的动力学强弱性整体的变化趋势符合拓扑约束理论,表现为随着r变大,GexAsySe1-x-y系统的m整体上呈现降低的趋势,但是当r大于2.2,m值并不严格随着r的变大而减小,r为2.6的Ge10As40Se50硫系玻璃存在的Se链结构影响了网络结构稳定性,导致其强弱性指数m偏高。
, authors=周鹏
1, 赵华
1, 祖成奎
1, 郭腾霄
2, 徐建洁
2, 刘永华
1, 陶海征
3, 石凯文
3, 张瑞
1, 陈玮
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, correspAuthorsNote=
祖成奎(1964—),男,博士,教授。
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ZHOU Peng (1990-), male, Master candidate. E-mail: 695943489@qq.com
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周鹏(1990—),男,硕士研究生。
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周鹏(1990—),男,硕士研究生。
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