Article(id=1322612314889634657, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612265061306700, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.2020.05.20190673, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1570723200000, receivedDateStr=2019-10-11, revisedDate=1572451200000, revisedDateStr=2019-10-31, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264948817, onlineDateStr=2026-10-29, pubDate=1589904000000, pubDateStr=2020-05-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264948817, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264948817, creator=13701087609, updateTime=1793264948817, updator=13701087609, issue=Issue{id=1322612265061306700, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='5', pageStart='615', pageEnd='786', issueExtLink='null', onlineDate='null', pubDate='1589904000000', pubDateStr='2020-05-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264936938, creator='13701087609', updateTime=1793276961694, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322662700602208333, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612265061306700, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322662700602208334, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612265061306700, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=753, endPage=760, ext={EN=ArticleExt(id=1322612315061601122, articleId=1322612314889634657, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation of Attapulgite/g-C3N4/LaCoO3 Composites and Their Performance of Photocatalytic Desulfurization, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

ATP/g-C3N4 (graphitic carbon nitride) consisting of g-C3N4 film in-situ growth on the surface of attapulgite (ATP) rod was prepared via a hydrothermal process. Then ATP/g-C3N4 was used as a carrier to uniformly load LaCoO3 nano-particles to prepare Z-scheme ATP/g-C3N4/LaCoO3 heterojunction photocatalysts. The samples obtained were characterized by X-ray diffraction, transmission electron microscopy, ultraviolet-visible, photoluminescence, Brunauer-Emmett-Teller, specific surface area analysis and photo electrochemical analysis. The oxidative removal ability of ATP/g-C3N4/LaCoO3 at different loadings of LaCoO3 to benzothiophene (DBT) in model gasoline was investigated under visible light. The results show that ATP/g-C3N4/LaCoO3 composites dramatically enhance the visible light response, the absorption capacity and the separation of photogenerated electron-hole pairs, compared to ATP/g-C3N4 andLaCoO3. After 150-min irradiation, the desulfurizing rate of 50%-ATP/g-C3N4/LaCoO3 can achieve 85.3%.

, authors=Shixiang ZUO, Hongye WU, Wenjie LIU, Xiazhang LI, Rong XU, Chao YAO, Fengqin WU, Jing ZHONG, authorsList=Shixiang ZUO, Hongye WU, Wenjie LIU, Xiazhang LI, Rong XU, Chao YAO, Fengqin WU, Jing ZHONG, authorCompany=null, correspAuthors=Chao YAO, authorNote=

ZUO Shixiang (1984-), male, Ph.D, Assistant Researcher. E-mail:

, correspAuthorsNote=
YAO Chao (1969-), male, Ph.D, Professor. E-mail:
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通过水热法在凹凸棒石(ATP)棒晶表面原位生长石墨相氮化碳(g-C3N4)膜层合成了ATP/g-C3N4复合材料,然后以ATP/g-C3N4为载体,在其表面均匀负载纳米钴酸镧(LaCoO3)粒子,制备了Z-型异质结构的ATP/g-C3N4/LaCoO3光催化材料。利用X射线粉末衍射、透射电镜、紫外-可见吸收光谱、荧光发射光谱、N2吸附-脱附和光电化学等技术对样品进行表征。在可见光照射下,考察了LaCoO3不同负载量下ATP/g-C3N4/LaCoO3对模拟汽油中的苯并噻吩(DBT)的氧化脱除能力。结果表明:与ATP/g-C3N4和LaCoO3相比,ATP/g-C3N4/LaCoO3大幅提高了可见光响应、吸收能力和光生电子-空穴对的分离效率。当光照时间为150 min时,50%-ATP/g-C3N4/LaCoO3对模拟汽油中的DBT脱除率可达85.3%。

, authors=左士祥, 吴红叶, 刘文杰, 李霞章, 徐荣, 姚超, 吴凤芹, 钟璟, authorsList=左士祥, 吴红叶, 刘文杰, 李霞章, 徐荣, 姚超, 吴凤芹, 钟璟, authorCompany=null, correspAuthors=姚超, authorNote=

左士祥(1984—),男,博士,助理研究员。

, correspAuthorsNote=
姚超(1969—),男,博士,教授。
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凹凸棒石/g-C3N4/LaCoO3复合材料的制备及其光催化脱硫性能
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左士祥 , 吴红叶 , 刘文杰 , 李霞章 , 徐荣 , 姚超 , 吴凤芹 , 钟璟
硅酸盐学报 | 2020,48(5): 753-760
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硅酸盐学报 | 2020 , 48 (5) : 753 -760
凹凸棒石/g-C3N4/LaCoO3复合材料的制备及其光催化脱硫性能
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左士祥 , 吴红叶, 刘文杰, 李霞章, 徐荣, 姚超 , 吴凤芹, 钟璟
作者信息
  • 常州大学石油化工学院,江苏省先进催化与绿色制造协同创新中心,江苏 常州 213164
通讯作者:
姚超(1969—),男,博士,教授。
作者简介:

左士祥(1984—),男,博士,助理研究员。

Preparation of Attapulgite/g-C3N4/LaCoO3 Composites and Their Performance of Photocatalytic Desulfurization
Shixiang ZUO , Hongye WU, Wenjie LIU, Xiazhang LI, Rong XU, Chao YAO , Fengqin WU, Jing ZHONG
Affiliations
  • Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, Jiangsu, China
  • Corresponding Author:
    YAO Chao (1969-), male, Ph.D, Professor. E-mail:

    ZUO Shixiang (1984-), male, Ph.D, Assistant Researcher. E-mail:

出版时间: 2020-05-20 doi: 10.14062/j.issn.0454-5648.2020.05.20190673
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通过水热法在凹凸棒石(ATP)棒晶表面原位生长石墨相氮化碳(g-C3N4)膜层合成了ATP/g-C3N4复合材料,然后以ATP/g-C3N4为载体,在其表面均匀负载纳米钴酸镧(LaCoO3)粒子,制备了Z-型异质结构的ATP/g-C3N4/LaCoO3光催化材料。利用X射线粉末衍射、透射电镜、紫外-可见吸收光谱、荧光发射光谱、N2吸附-脱附和光电化学等技术对样品进行表征。在可见光照射下,考察了LaCoO3不同负载量下ATP/g-C3N4/LaCoO3对模拟汽油中的苯并噻吩(DBT)的氧化脱除能力。结果表明:与ATP/g-C3N4和LaCoO3相比,ATP/g-C3N4/LaCoO3大幅提高了可见光响应、吸收能力和光生电子-空穴对的分离效率。当光照时间为150 min时,50%-ATP/g-C3N4/LaCoO3对模拟汽油中的DBT脱除率可达85.3%。

凹凸棒石  /  石墨相氮化碳  /  钴酸镧  /  光催化脱硫  /  异质结

ATP/g-C3N4 (graphitic carbon nitride) consisting of g-C3N4 film in-situ growth on the surface of attapulgite (ATP) rod was prepared via a hydrothermal process. Then ATP/g-C3N4 was used as a carrier to uniformly load LaCoO3 nano-particles to prepare Z-scheme ATP/g-C3N4/LaCoO3 heterojunction photocatalysts. The samples obtained were characterized by X-ray diffraction, transmission electron microscopy, ultraviolet-visible, photoluminescence, Brunauer-Emmett-Teller, specific surface area analysis and photo electrochemical analysis. The oxidative removal ability of ATP/g-C3N4/LaCoO3 at different loadings of LaCoO3 to benzothiophene (DBT) in model gasoline was investigated under visible light. The results show that ATP/g-C3N4/LaCoO3 composites dramatically enhance the visible light response, the absorption capacity and the separation of photogenerated electron-hole pairs, compared to ATP/g-C3N4 andLaCoO3. After 150-min irradiation, the desulfurizing rate of 50%-ATP/g-C3N4/LaCoO3 can achieve 85.3%.

attapulgite  /  graphitic carbon nitride  /  lanthanum cobalt  /  photocatalytic desulfurization  /  heterojunction
左士祥, 吴红叶, 刘文杰, 李霞章, 徐荣, 姚超, 吴凤芹, 钟璟. 凹凸棒石/g-C3N4/LaCoO3复合材料的制备及其光催化脱硫性能. 硅酸盐学报, 2020 , 48 (5) : 753 -760 . DOI: 10.14062/j.issn.0454-5648.2020.05.20190673
Shixiang ZUO, Hongye WU, Wenjie LIU, Xiazhang LI, Rong XU, Chao YAO, Fengqin WU, Jing ZHONG. Preparation of Attapulgite/g-C3N4/LaCoO3 Composites and Their Performance of Photocatalytic Desulfurization[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (5) : 753 -760 . DOI: 10.14062/j.issn.0454-5648.2020.05.20190673
  • 国家自然科学基金(51702026)
  • 江苏省先进催化与绿色制造协同创新中心人才支持项目(ACGM2016-06-11)
  • 江苏省重点研发计划(BE2018649)
  • 常州市科技支撑计划(CE20185007; CE20185031)
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2020年第48卷第5期
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doi: 10.14062/j.issn.0454-5648.2020.05.20190673
  • 接收时间:2019-10-11
  • 首发时间:2026-10-29
  • 出版时间:2020-05-20
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  • 收稿日期:2019-10-11
  • 修回日期:2019-10-31
基金
国家自然科学基金(51702026)
江苏省先进催化与绿色制造协同创新中心人才支持项目(ACGM2016-06-11)
江苏省重点研发计划(BE2018649)
常州市科技支撑计划(CE20185007; CE20185031)
作者信息
    常州大学石油化工学院,江苏省先进催化与绿色制造协同创新中心,江苏 常州 213164

通讯作者:

姚超(1969—),男,博士,教授。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.2020.05.20190673
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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