Article(id=1322622798674113163, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190828, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1576598400000, receivedDateStr=2019-12-18, revisedDate=1579190400000, revisedDateStr=2020-01-17, acceptedDate=null, acceptedDateStr=null, onlineDate=1793267448347, onlineDateStr=2026-10-29, pubDate=1595174400000, pubDateStr=2020-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793267448347, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793267448347, creator=13701087609, updateTime=1793267448347, updator=13701087609, issue=Issue{id=1322622757339250965, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='7', pageStart='939', pageEnd='1144', issueExtLink='null', onlineDate='null', pubDate='1595174400000', pubDateStr='2020-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793267438492, creator='13701087609', updateTime=1793277091258, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663244053992200, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663244053992201, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1122, endPage=1127, ext={EN=ArticleExt(id=1322622798862856844, articleId=1322622798674113163, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation of Molecular Sieve and Diatomite Composite by Hydrothermal Method and Its Adsorption Performance, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

A diatomite composite with a molecular sieve structure was prepared via acid hydrothermal treatment, and its adsorption performance was evaluated by a saturated adsorption rate of methylene blue in solution. The results show that a phase Variscite 10 with a molecular sieve structure can be formed by hydrothermal treatment. The saturated adsorption capacity of the composite with the specific surface area of 96.02 m2/g is 98.60 mg/g, which is 298.79 times greater than that of the raw diatomite. The size and crystallinity of the molecular sieve particles increase and the diatomite shell with tubular structure destroys as the reaction time increases, leading to the decrease of the adsorption performance of methylene blue. The optimum parameters for hydrothermal treatment are mixed acid of 10%(in mass fraction), reaction temperature of 180 ℃ and reaction time of 2 h.

, authors=Shiyu DAI, Lin ZHANG, Pengyuan QI, Ling WANG, Weimin MA, authorsList=Shiyu DAI, Lin ZHANG, Pengyuan QI, Ling WANG, Weimin MA, authorCompany=null, correspAuthors=Pengyuan QI, authorNote=

DAI Shiyu (1975-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
QI Pengyuan (1981-), male, Associate Professor. E-mail:
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利用酸性水热处理工艺制备具有分子筛结构的硅藻土复合材料,并通过对溶液中亚甲基蓝的饱和吸附率来评价其吸附性能。结果表明:水热处理能够生成具有分子筛结构的新相Variscite 10,当反应时间为2 h时,生成的分子筛/硅藻土复合材料性能达到最佳,其比表面积为96.02 m2/g,饱和吸附量为98.60 mg/g,比硅藻土原矿增加298.79倍;随着水热反应时间的增加,新相分子筛颗粒变大、结晶度提高,且原有的硅藻壳体管状结构被破坏、比表面积变小,导致对亚甲基蓝的吸附性能降低。水热处理的最佳工艺参数为混合酸质量分数为10%、反应温度180 ℃、反应时长2 h。

, authors=戴时雨, 张林, 齐鹏远, 王岭, 马伟民, authorsList=戴时雨, 张林, 齐鹏远, 王岭, 马伟民, authorCompany=null, correspAuthors=齐鹏远, authorNote=

戴时雨(1975—),男,博士研究生,讲师。

, correspAuthorsNote=
齐鹏远(1981—),男,硕士,副教授。
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水热法制备分子筛/硅藻土复合材料及其吸附性能
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戴时雨 , 张林 , 齐鹏远 , 王岭 , 马伟民
硅酸盐学报 | 研究论文 2020,48(7): 1122-1127
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硅酸盐学报 |研究论文 2020 , 48 (7) : 1122 -1127
水热法制备分子筛/硅藻土复合材料及其吸附性能
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戴时雨 , 张林, 齐鹏远 , 王岭, 马伟民
作者信息
  • 营口理工学院材料科学与工程系,辽宁 营口 115014
通讯作者:
齐鹏远(1981—),男,硕士,副教授。
作者简介:

戴时雨(1975—),男,博士研究生,讲师。

Preparation of Molecular Sieve and Diatomite Composite by Hydrothermal Method and Its Adsorption Performance
Shiyu DAI , Lin ZHANG, Pengyuan QI , Ling WANG, Weimin MA
Affiliations
  • Department of Materials Science and Engineering, Yingkou Institute of Technology, Yingkou 115014, Liaoning, China
  • Corresponding Author:
    QI Pengyuan (1981-), male, Associate Professor. E-mail:

    DAI Shiyu (1975-), male, Doctoral candidate. E-mail:

出版时间: 2020-07-20 doi: 10.14062/j.issn.0454-5648.20190828
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利用酸性水热处理工艺制备具有分子筛结构的硅藻土复合材料,并通过对溶液中亚甲基蓝的饱和吸附率来评价其吸附性能。结果表明:水热处理能够生成具有分子筛结构的新相Variscite 10,当反应时间为2 h时,生成的分子筛/硅藻土复合材料性能达到最佳,其比表面积为96.02 m2/g,饱和吸附量为98.60 mg/g,比硅藻土原矿增加298.79倍;随着水热反应时间的增加,新相分子筛颗粒变大、结晶度提高,且原有的硅藻壳体管状结构被破坏、比表面积变小,导致对亚甲基蓝的吸附性能降低。水热处理的最佳工艺参数为混合酸质量分数为10%、反应温度180 ℃、反应时长2 h。

水热法  /  分子筛  /  比表面积  /  吸附性能

A diatomite composite with a molecular sieve structure was prepared via acid hydrothermal treatment, and its adsorption performance was evaluated by a saturated adsorption rate of methylene blue in solution. The results show that a phase Variscite 10 with a molecular sieve structure can be formed by hydrothermal treatment. The saturated adsorption capacity of the composite with the specific surface area of 96.02 m2/g is 98.60 mg/g, which is 298.79 times greater than that of the raw diatomite. The size and crystallinity of the molecular sieve particles increase and the diatomite shell with tubular structure destroys as the reaction time increases, leading to the decrease of the adsorption performance of methylene blue. The optimum parameters for hydrothermal treatment are mixed acid of 10%(in mass fraction), reaction temperature of 180 ℃ and reaction time of 2 h.

hydrothermal treatment  /  molecular sieve  /  specific surface area  /  adsorption performance
戴时雨, 张林, 齐鹏远, 王岭, 马伟民. 水热法制备分子筛/硅藻土复合材料及其吸附性能. 硅酸盐学报, 2020 , 48 (7) : 1122 -1127 . DOI: 10.14062/j.issn.0454-5648.20190828
Shiyu DAI, Lin ZHANG, Pengyuan QI, Ling WANG, Weimin MA. Preparation of Molecular Sieve and Diatomite Composite by Hydrothermal Method and Its Adsorption Performance[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (7) : 1122 -1127 . DOI: 10.14062/j.issn.0454-5648.20190828
  • 辽宁省自然科学基金资助项目(20180550516)
  • 辽宁省教育厅科学研究资助项目(L2019005)
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doi: 10.14062/j.issn.0454-5648.20190828
  • 接收时间:2019-12-18
  • 首发时间:2026-10-29
  • 出版时间:2020-07-20
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  • 收稿日期:2019-12-18
  • 修回日期:2020-01-17
基金
辽宁省自然科学基金资助项目(20180550516)
辽宁省教育厅科学研究资助项目(L2019005)
作者信息
    营口理工学院材料科学与工程系,辽宁 营口 115014

通讯作者:

齐鹏远(1981—),男,硕士,副教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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