Article(id=1322636235986809275, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636193100050547, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190796, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1575820800000, receivedDateStr=2019-12-09, revisedDate=1578585600000, revisedDateStr=2020-01-10, acceptedDate=null, acceptedDateStr=null, onlineDate=1793270652051, onlineDateStr=2026-10-29, pubDate=1600531200000, pubDateStr=2020-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793270652051, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793270652051, creator=13701087609, updateTime=1793270652051, updator=13701087609, issue=Issue{id=1322636193100050547, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='9', pageStart='1353', pageEnd='1510', issueExtLink='null', onlineDate='null', pubDate='1594569600000', pubDateStr='2020-07-13', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793270641826, creator='13701087609', updateTime=1793270641826, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=1494, endPage=1504, ext={EN=ArticleExt(id=1322636236389462460, articleId=1322636235986809275, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Self-propagating High-temperature Synthesis of TiC Coating on Graphite Flakes and Its Effect on Properties of Refractory Castables, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

In order to solve the problem of high porosity of refractory castables due to the poor water wettability, graphite flakes (GF) were coated by TiC using titanium powders (Ti) via self-propagating high-temperature synthesis (SHS). The phase composition and microstructure of the products were investigated by X-ray diffraction, scanning electron microscopy and energy dispersive spectrometry. The water wettability of TiC-coated GF (CT) was evaluated by Zeta potential measurement, sedimentation test and water contact angle measurement, respectively. The results show that TiC coating with a continuous and uniform thickness of 763 nm is formed on the GF surface. Compared to uncoated GF and the sample with n(GF):n(TiC)=1:1 (GT) prepared by mechanical mixing, the sample CT has the maximum Zeta potential value, no delamination occurs when the sample CT disperses in water, and the contact angles with water is 26°. In addition, the physical properties, oxidation resistance and slag corrosion resistance of Al2O3-MgO refractory castables with GF, GT, and CT as well as castables without graphite (labled as CGF, CGT, CCT, and C0, respectively) were also determined. The apparent porosity of CCT castable is 13.4%, which is 39.37% and 11.26% lower than that of CGF and CGT castables, respectively. The decarbonized depth of CCT castable is 8.0 mm, which is 14.89% and 8.05% lower than that of CGF and CGT castables, respectively. The slag corrosion area of CCT castable is 29% , which is 19.44%、6.45% and 3.33% lower than that of C0, CGF and CGT castables, respectively.

, authors=Chenglin ZHANG, Guoqing XIAO, Donghai DING, Yun REN, Yunfei ZANG, Jianjun CHEN, authorsList=Chenglin ZHANG, Guoqing XIAO, Donghai DING, Yun REN, Yunfei ZANG, Jianjun CHEN, authorCompany=null, correspAuthors=Guoqing XIAO, authorNote=

ZHANG Chenglin (1995-), female, Master candidate. E-mail:

, correspAuthorsNote=
XIAO Guoqing (1967-), male, Professor. E-mail:
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以鳞片石墨(GF)和钛粉(Ti)为原料,通过自蔓延高温合成法(SHS)在GF表面制备碳化钛(TiC)包覆层,利用X射线衍射仪、扫描电子显微镜和能谱仪对产物物相组成和显微结构进行研究,并分别通过Zeta电位测试、沉降实验及水滴角测试考察TiC包覆GF[碳化钛包覆鳞片石墨(CT)]的水润湿性。结果表明:GF表面形成了连续、厚度均匀(约为763 nm)的TiC包覆层,与GF和n(GF):n(TiC)=1:1(n为摩尔)时的机械混合粉(GT)相比,CT具有最高的Zeta电位绝对值,在水中未出现分层现象,且水润湿角为26°。并研究以GF为碳源的Al2O3-MgO质耐火浇注料(CGF)、以GT为碳源的Al2O3-MgO质耐火浇注料(CGT)、以CT为碳源的Al2O3-MgO质耐火浇注料(CCT)和未引入碳源的Al2O3-MgO质耐火浇注料(C0)的物理性能、抗氧化性能和抗渣性能。结果表明:经110 ℃烘干,CCT浇注料的显气孔率为13.4%,比CGF、CGT浇注料分别降低39.37%和11.26%;CCT浇注料的脱碳层厚度为8.0 mm,比CGF、CGT浇注料分别降低14.89%和8.05%;CCT浇注料的熔渣侵蚀面积为29%,比C0、CGF、CGT浇注料分别降低19.44%、6.45%和3.33%。

, authors=张成林, 肖国庆, 丁冬海, 任耘, 臧云飞, 陈建军, authorsList=张成林, 肖国庆, 丁冬海, 任耘, 臧云飞, 陈建军, authorCompany=null, correspAuthors=肖国庆, authorNote=

张成林(1995—),女,硕士研究生。

, correspAuthorsNote=
肖国庆(1967—),男,教授。
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ZHANG Chenglin (1995-), female, Master candidate. E-mail:

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张成林(1995—),女,硕士研究生。

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张成林(1995—),女,硕士研究生。

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自蔓延TiC包覆鳞片石墨及其对耐火浇注料性能的影响
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张成林 , 肖国庆 , 丁冬海 , 任耘 , 臧云飞 , 陈建军
硅酸盐学报 | 2020,48(9): 1494-1504
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硅酸盐学报 | 2020 , 48 (9) : 1494 -1504
自蔓延TiC包覆鳞片石墨及其对耐火浇注料性能的影响
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张成林 , 肖国庆 , 丁冬海, 任耘, 臧云飞, 陈建军
作者信息
  • 西安建筑科技大学材料科学与工程学院,西安 710055
通讯作者:
肖国庆(1967—),男,教授。
作者简介:

张成林(1995—),女,硕士研究生。

Self-propagating High-temperature Synthesis of TiC Coating on Graphite Flakes and Its Effect on Properties of Refractory Castables
Chenglin ZHANG , Guoqing XIAO , Donghai DING, Yun REN, Yunfei ZANG, Jianjun CHEN
Affiliations
  • College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
  • Corresponding Author:
    XIAO Guoqing (1967-), male, Professor. E-mail:

    ZHANG Chenglin (1995-), female, Master candidate. E-mail:

出版时间: 2020-09-20 doi: 10.14062/j.issn.0454-5648.20190796
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以鳞片石墨(GF)和钛粉(Ti)为原料,通过自蔓延高温合成法(SHS)在GF表面制备碳化钛(TiC)包覆层,利用X射线衍射仪、扫描电子显微镜和能谱仪对产物物相组成和显微结构进行研究,并分别通过Zeta电位测试、沉降实验及水滴角测试考察TiC包覆GF[碳化钛包覆鳞片石墨(CT)]的水润湿性。结果表明:GF表面形成了连续、厚度均匀(约为763 nm)的TiC包覆层,与GF和n(GF):n(TiC)=1:1(n为摩尔)时的机械混合粉(GT)相比,CT具有最高的Zeta电位绝对值,在水中未出现分层现象,且水润湿角为26°。并研究以GF为碳源的Al2O3-MgO质耐火浇注料(CGF)、以GT为碳源的Al2O3-MgO质耐火浇注料(CGT)、以CT为碳源的Al2O3-MgO质耐火浇注料(CCT)和未引入碳源的Al2O3-MgO质耐火浇注料(C0)的物理性能、抗氧化性能和抗渣性能。结果表明:经110 ℃烘干,CCT浇注料的显气孔率为13.4%,比CGF、CGT浇注料分别降低39.37%和11.26%;CCT浇注料的脱碳层厚度为8.0 mm,比CGF、CGT浇注料分别降低14.89%和8.05%;CCT浇注料的熔渣侵蚀面积为29%,比C0、CGF、CGT浇注料分别降低19.44%、6.45%和3.33%。

自蔓延高温合成  /  碳化钛  /  鳞片石墨  /  水润湿性  /  浇注料  /  显气孔率

In order to solve the problem of high porosity of refractory castables due to the poor water wettability, graphite flakes (GF) were coated by TiC using titanium powders (Ti) via self-propagating high-temperature synthesis (SHS). The phase composition and microstructure of the products were investigated by X-ray diffraction, scanning electron microscopy and energy dispersive spectrometry. The water wettability of TiC-coated GF (CT) was evaluated by Zeta potential measurement, sedimentation test and water contact angle measurement, respectively. The results show that TiC coating with a continuous and uniform thickness of 763 nm is formed on the GF surface. Compared to uncoated GF and the sample with n(GF):n(TiC)=1:1 (GT) prepared by mechanical mixing, the sample CT has the maximum Zeta potential value, no delamination occurs when the sample CT disperses in water, and the contact angles with water is 26°. In addition, the physical properties, oxidation resistance and slag corrosion resistance of Al2O3-MgO refractory castables with GF, GT, and CT as well as castables without graphite (labled as CGF, CGT, CCT, and C0, respectively) were also determined. The apparent porosity of CCT castable is 13.4%, which is 39.37% and 11.26% lower than that of CGF and CGT castables, respectively. The decarbonized depth of CCT castable is 8.0 mm, which is 14.89% and 8.05% lower than that of CGF and CGT castables, respectively. The slag corrosion area of CCT castable is 29% , which is 19.44%、6.45% and 3.33% lower than that of C0, CGF and CGT castables, respectively.

self-propagating high-temperature synthesis  /  titanium carbide  /  graphite flakes  /  water wettability  /  castables  /  apparent porosity
张成林, 肖国庆, 丁冬海, 任耘, 臧云飞, 陈建军. 自蔓延TiC包覆鳞片石墨及其对耐火浇注料性能的影响. 硅酸盐学报, 2020 , 48 (9) : 1494 -1504 . DOI: 10.14062/j.issn.0454-5648.20190796
Chenglin ZHANG, Guoqing XIAO, Donghai DING, Yun REN, Yunfei ZANG, Jianjun CHEN. Self-propagating High-temperature Synthesis of TiC Coating on Graphite Flakes and Its Effect on Properties of Refractory Castables[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (9) : 1494 -1504 . DOI: 10.14062/j.issn.0454-5648.20190796
  • 国家自然科学基金(51572212; 51772236)
  • 陕西省教育厅重点实验室科研计划项目(15JS053)
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doi: 10.14062/j.issn.0454-5648.20190796
  • 接收时间:2019-12-09
  • 首发时间:2026-10-29
  • 出版时间:2020-09-20
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  • 收稿日期:2019-12-09
  • 修回日期:2020-01-10
基金
国家自然科学基金(51572212; 51772236)
陕西省教育厅重点实验室科研计划项目(15JS053)
作者信息
    西安建筑科技大学材料科学与工程学院,西安 710055

通讯作者:

肖国庆(1967—),男,教授。
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2种不同金属材料的力学参数
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属
Genus
种数
Number of
species
占总种数比例
Percentage of total
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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