Article(id=1322636198703640734, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636193100050547, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190763, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1574524800000, receivedDateStr=2019-11-24, revisedDate=1577289600000, revisedDateStr=2019-12-26, acceptedDate=null, acceptedDateStr=null, onlineDate=1793270643163, onlineDateStr=2026-10-29, pubDate=1600531200000, pubDateStr=2020-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793270643163, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793270643163, creator=13701087609, updateTime=1793270643163, updator=13701087609, issue=Issue{id=1322636193100050547, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='9', pageStart='1353', pageEnd='1510', issueExtLink='null', onlineDate='null', pubDate='1594569600000', pubDateStr='2020-07-13', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793270641826, creator='13701087609', updateTime=1793270641826, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=1424, endPage=1429, ext={EN=ArticleExt(id=1322636198930133151, articleId=1322636198703640734, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Limiting Current Oxygen Sensor Based on Y, Fe co-doped CaZrO₃-based Materials As Dense Diffusion Barrier Layer, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Y-, Fe co-doped CaZrO₃ (Y_0.08Ca_0.92Zr_1-xFe_xO_3-δ (x=0.3, 0.4, 0.5)) was synthesized by solid state reaction method. The crystal phase composition, microstructure, oxygen ionic conductivity, total conductivity and sensing properties were investigated. The result suggests that a highly orthorhombic perovskite structure and the increase of Fe-doped amount is unfavorable for the formation of single orthorhombic perovskite structre. The total electrical conductivity and ionic conductivity increase with Fe-doped amount increasing. The oxygen sensor shows good limiting current plateau in the range of 800-950 ℃. The linear relationship between limiting current (lgI_L) and 1 000/T can described as follows: lgI_L =3.215-2.101 3×(1 000/T)and the activation energy of oxygen ion is 0.417 eV. At 750 ℃、1.0%≤x(O₂)≤7.5%, the relationship between limiting current (I_L) and oxygen amount (x(O₂)) can be expressed: I_L= 7.047 6+3.875 1×x(O₂).

, authors=Ke SHAN¹, Aijia YANG¹, Fengrui ZHAI¹, Zhe YAO², Nan LI¹, Zhipeng XIE³, Zhongzhou YI¹, authorsList=Ke SHAN, Aijia YANG, Fengrui ZHAI, Zhe YAO, Nan LI, Zhipeng XIE, Zhongzhou YI, authorCompany=null, correspAuthors=null, authorNote=, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322636199169208480, articleId=1322636198703640734, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=钇铁共掺杂锆酸钙致密扩散层极限电流型氧传感器, columnId=null, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用固相反应法合成钇铁共掺杂锆酸钙（Y_0.08Ca_0.92Zr_1-xFe_xO_3-δ（x=0.3，0.4，0.5））混合导体材料，以钇铁共掺杂锆酸钙为致密扩散障碍层，以YSZ为泵氧层，制备了极限电流氧传感器。结果表明：Y_0.08Ca_0.92Zr_1-xFe_xO_3-δ的主晶相为菱方钙钛矿结构；随Fe掺杂量的增加，Y_0.08Ca_0.92Zr_1-xFe_xO_3-δ材料的总电导率和离子电导率均增大；在800~950 ℃范围，氧传感器具有良好的极限电流，出现极限电流的温度随Fe掺杂量的增加而降低，极限电流（lgI_L）与1000/T呈线性关系：lgI_L=3.215-2.1013×（1 000/T），氧离子扩散激活能为0.417 eV。在750℃、1.0%（摩尔分数）≤x（O₂）≤7.5%时，极限电流I_L与氧含量x（O₂）间的关系式为：I_L=7.0476+3.8751×x（O₂）。

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SHAN Ke (1978-), female, Ph.D., Associate Professor. E-mail: shankekeshan@163.com

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SHAN Ke (1978-), female, Ph.D., Associate Professor. E-mail: shankekeshan@163.com

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单科（1978—），女，博士，副教授。

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单科（1978—），女，博士，副教授。

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