Article(id=1322636209550119581, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636193100050547, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190719, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1573574400000, receivedDateStr=2019-11-13, revisedDate=1578499200000, revisedDateStr=2020-01-09, acceptedDate=null, acceptedDateStr=null, onlineDate=1793270645748, onlineDateStr=2026-10-29, pubDate=1600531200000, pubDateStr=2020-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793270645748, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793270645748, creator=13701087609, updateTime=1793270645748, updator=13701087609, issue=Issue{id=1322636193100050547, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='9', pageStart='1353', pageEnd='1510', issueExtLink='null', onlineDate='null', pubDate='1594569600000', pubDateStr='2020-07-13', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793270641826, creator='13701087609', updateTime=1793270641826, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=1468, endPage=1473, ext={EN=ArticleExt(id=1322636211345281695, articleId=1322636209550119581, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Bi³⁺ Concentration on Photoluminescence Properties of Y₂O₃:Bi³⁺ Phosphors, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Y₂O₃:xBi³⁺ (x=0.05-1.0% (mole fraction)) phosphors were synthesized by a solid-phase reaction route. Effect of Bi³⁺ concentration on the phase composition, microstructure and photoluminescence (PL) performance was investigated. The results show that the lattice parameter and cell volume of Y₂O₃ host increase with the increase of Bi³⁺ concentration. In addition, the phosphors are equiaxed grains, and the grain size increases gradually from 250 to 600 nm with the Bi³⁺ concentration increasing. The emission spectra of Y₂O₃:Bi³⁺ phosphors excited by ultraviolet light (λ_EX=335 nm) are composed of three broadband emission spectra centered at 370 nm, 410 nm and 483 nm. The ultraviolet-emission at 370 nm and blue-light emission at 410 nm appear due to ³A_u→¹A_g and ³E_u→¹A_g electron transitions of S₆ sites of Bi³⁺, respectively. The blue-green emission at 483 nm occurs due to ³B→¹A electron transition of C₂ sites of Bi³⁺. The Y₂O₃:0.25%Bi³⁺ phosphor shows the optimal PL performance. The concentration quenching occurs when Bi³⁺ concentration is higher than 0.25% due to the dipole-dipole interaction between Bi³⁺ ions. The color coordinate of Y₂O₃:0.25%Bi³⁺ is (0.159 2, 0.218 1), and the color rendering index Ra is 69.27, indicating that the as-synthesized blue-green phosphors have a broad application prospect in the field of white light-emitting diode.

, authors=Qian LI¹, Biao ZHANG¹, Zhongqi SHI¹, Yongfeng KANG², authorsList=Qian LI, Biao ZHANG, Zhongqi SHI, Yongfeng KANG, authorCompany=null, correspAuthors=Zhongqi SHI, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322636211563385504, articleId=1322636209550119581, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=Bi³⁺浓度对Y₂O₃基荧光粉发光性能的影响, columnId=null, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用高温固相法合成了Y₂O₃：xBi³⁺[x=0.05-1.00%（摩尔分数）]荧光粉，研究了Bi³⁺掺杂浓度对荧光粉相组成、微观形貌及发光性能的影响。结果表明：Bi³⁺掺杂量增加会引起Y₂O₃基质晶格膨胀和晶胞体积增大；荧光粉呈等轴状颗粒形貌，且随着Bi³⁺掺杂量的增加，粒径逐渐从250 nm增加到600 nm。Y₂O₃：xBi³⁺荧光粉在波长为335 nm的紫外光激发下，其发射光谱由370、410和483 nm 3个宽带发射组成。370 nm紫外光发射和410 nm蓝光发射分别是由Bi³⁺的S₆位点的³A_u→¹A_g和³E_u→¹A_g电子跃迁产生，483 nm蓝绿光发射是由C₂位点的³B→¹A电子跃迁产生。当Bi³⁺掺杂浓度为0.25%时，荧光粉发光性能最优；掺杂量大于0.25%时，由于Bi³⁺间的偶极-偶极相互作用，产生浓度猝灭现象。所制备的Y₂O₃：0.25%Bi³⁺荧光粉的色坐标为（0.1592、0.2181），显色指数Ra为69.27，表明这种蓝绿色荧光粉在白光LED领域具有良好应用前景。

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LI Qian (1994-), female, Master candidate. E-mail: 1252476405@qq.com

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LI Qian (1994-), female, Master candidate. E-mail: 1252476405@qq.com

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李倩（1994—），女，硕士研究生。

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李倩（1994—），女，硕士研究生。

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