Article(id=1322612228562473011, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612228126265395, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190691, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1571500800000, receivedDateStr=2019-10-20, revisedDate=1573142400000, revisedDateStr=2019-11-08, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264928236, onlineDateStr=2026-10-29, pubDate=1587312000000, pubDateStr=2020-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264928236, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264928236, creator=13701087609, updateTime=1793264928236, updator=13701087609, issue=Issue{id=1322612228126265395, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='4', pageStart='463', pageEnd='614', issueExtLink='null', onlineDate='null', pubDate='1587312000000', pubDateStr='2020-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264928132, creator='13701087609', updateTime=1793276729826, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322661728073138752, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612228126265395, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322661728073138753, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612228126265395, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=514, endPage=519, ext={EN=ArticleExt(id=1322612228717662260, articleId=1322612228562473011, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Molten Salt on Preparation of Zirconia Nanosheets, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

ZrO2 nanosheets were prepared at low temperature by a molten salt method with assistance of solvothermal process using zirconium chloride as zirconium source and ethanol as a solvent. The effects of salt type and content on the growth and morphology of zirconia crystals were investigated. The results show that monoclinic zirconia nanosheets with an average side length of 1.8 μm, a thickness of 70 nm and a width: thickness ratio of more than 10∶1 can be obtained when NaCl and Na3PO4 are used as composite molten salts and the mass ratio of precursor∶NaCl∶Na3PO4 is set to 10∶10∶1. The nanosheet shows single crystal structure with little defects, and the main exposed surface is (001) facet. The formation process in molten salts accords with a self-focusing mechanism, including dissolution, diffusion, adsorption and growth. The large percentage of (001) facet obtained is in reasonable agreement with that based on the theoretical calculation of surface energy.

, authors=Xuefeng LIU1, Jianmin LIU2, Yage LI1, Zijuan TANG1, Tao WANG1, Guo FENG2, Weihui JIANG1, 2, authorsList=Xuefeng LIU, Jianmin LIU, Yage LI, Zijuan TANG, Tao WANG, Guo FENG, Weihui JIANG, authorCompany=null, correspAuthors=Weihui JIANG, authorNote=

LIU Xuefeng (1992-), male, Master candidate. E-mail:

, correspAuthorsNote=
JIANG Weihui (1965-), male, Ph.D., Professor. E-mail:
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以四氯化锆为锆源,乙醇为溶剂,采用溶剂热辅助熔盐法低温煅烧制备氧化锆纳米片。研究并讨论了熔盐种类和用量对氧化锆晶体生长和形貌的影响。结果表明:以NaCl和Na3PO4的混合物为熔盐,且m(前驱体)∶m(NaCl)∶m(Na3PO4)=10∶10∶1时,可以得到平均边长超过1.8 μm,厚约70 nm,宽厚比大于10∶1的单斜氧化锆纳米片。纳米片为单晶结构,无明显缺陷,主要暴露面为(001)晶面,其在熔盐中的形成符合自聚焦机理,包括溶解、扩散、吸附和生长过程,(001)面主导的氧化锆纳米片与表面能的理论计算结果吻合。

, authors=刘雪枫1, 刘健敏2, 李亚格1, 唐紫娟1, 王涛1, 冯果2, 江伟辉1, 2, authorsList=刘雪枫, 刘健敏, 李亚格, 唐紫娟, 王涛, 冯果, 江伟辉, authorCompany=null, correspAuthors=江伟辉, authorNote=

刘雪枫(1992—),男,硕士研究生。

, correspAuthorsNote=
江伟辉(1965—),男,博士,教授。
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LIU Xuefeng (1992-), male, Master candidate. E-mail:

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LIU Xuefeng (1992-), male, Master candidate. E-mail:

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熔融盐对氧化锆纳米片合成的影响
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刘雪枫 1 , 刘健敏 2 , 李亚格 1 , 唐紫娟 1 , 王涛 1 , 冯果 2 , 江伟辉 1, 2
硅酸盐学报 | 2020,48(4): 514-519
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硅酸盐学报 | 2020 , 48 (4) : 514 -519
熔融盐对氧化锆纳米片合成的影响
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刘雪枫(1992—),男,硕士研究生。

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刘雪枫1 , 刘健敏2, 李亚格1, 唐紫娟1, 王涛1, 冯果2, 江伟辉1, 2
作者信息
  • 1.景德镇陶瓷大学材料科学与工程学院,江西 景德镇 333403
  • 2.国家日用及建筑陶瓷工程技术研究中心,江西 景德镇 333001
通讯作者:
江伟辉(1965—),男,博士,教授。
作者简介:

刘雪枫(1992—),男,硕士研究生。

Effect of Molten Salt on Preparation of Zirconia Nanosheets
Xuefeng LIU1 , Jianmin LIU2, Yage LI1, Zijuan TANG1, Tao WANG1, Guo FENG2, Weihui JIANG1, 2
Affiliations
  • 1.School of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333403, Jiangxi, China
  • 2.National Engineering Research Center for Domestic and Building Ceramics, Jingdezhen 333001, Jiangxi, China
  • Corresponding Author:
    JIANG Weihui (1965-), male, Ph.D., Professor. E-mail:

    LIU Xuefeng (1992-), male, Master candidate. E-mail:

出版时间: 2020-04-20 doi: 10.14062/j.issn.0454-5648.20190691
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以四氯化锆为锆源,乙醇为溶剂,采用溶剂热辅助熔盐法低温煅烧制备氧化锆纳米片。研究并讨论了熔盐种类和用量对氧化锆晶体生长和形貌的影响。结果表明:以NaCl和Na3PO4的混合物为熔盐,且m(前驱体)∶m(NaCl)∶m(Na3PO4)=10∶10∶1时,可以得到平均边长超过1.8 μm,厚约70 nm,宽厚比大于10∶1的单斜氧化锆纳米片。纳米片为单晶结构,无明显缺陷,主要暴露面为(001)晶面,其在熔盐中的形成符合自聚焦机理,包括溶解、扩散、吸附和生长过程,(001)面主导的氧化锆纳米片与表面能的理论计算结果吻合。

熔盐法  /  氧化锆纳米片  /  (001)晶面  /  自聚焦

ZrO2 nanosheets were prepared at low temperature by a molten salt method with assistance of solvothermal process using zirconium chloride as zirconium source and ethanol as a solvent. The effects of salt type and content on the growth and morphology of zirconia crystals were investigated. The results show that monoclinic zirconia nanosheets with an average side length of 1.8 μm, a thickness of 70 nm and a width: thickness ratio of more than 10∶1 can be obtained when NaCl and Na3PO4 are used as composite molten salts and the mass ratio of precursor∶NaCl∶Na3PO4 is set to 10∶10∶1. The nanosheet shows single crystal structure with little defects, and the main exposed surface is (001) facet. The formation process in molten salts accords with a self-focusing mechanism, including dissolution, diffusion, adsorption and growth. The large percentage of (001) facet obtained is in reasonable agreement with that based on the theoretical calculation of surface energy.

molten salt method  /  zirconium dioxide nanosheet  /  (001) facet  /  self-focusing
刘雪枫, 刘健敏, 李亚格, 唐紫娟, 王涛, 冯果, 江伟辉. 熔融盐对氧化锆纳米片合成的影响. 硅酸盐学报, 2020 , 48 (4) : 514 -519 . DOI: 10.14062/j.issn.0454-5648.20190691
Xuefeng LIU, Jianmin LIU, Yage LI, Zijuan TANG, Tao WANG, Guo FENG, Weihui JIANG. Effect of Molten Salt on Preparation of Zirconia Nanosheets[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (4) : 514 -519 . DOI: 10.14062/j.issn.0454-5648.20190691
  • 国家自然科学基金(51662016; 51962014)
  • 江西省重点研发计划(20192BBEL50022)
  • 江西省教育厅重点项目(GJJ180699)
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2020年第48卷第4期
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doi: 10.14062/j.issn.0454-5648.20190691
  • 接收时间:2019-10-20
  • 首发时间:2026-10-29
  • 出版时间:2020-04-20
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  • 收稿日期:2019-10-20
  • 修回日期:2019-11-08
基金
国家自然科学基金(51662016; 51962014)
江西省重点研发计划(20192BBEL50022)
江西省教育厅重点项目(GJJ180699)
作者信息
    1.景德镇陶瓷大学材料科学与工程学院,江西 景德镇 333403
    2.国家日用及建筑陶瓷工程技术研究中心,江西 景德镇 333001

通讯作者:

江伟辉(1965—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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