Article(id=1322612242953130162, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612228126265395, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190620, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1567785600000, receivedDateStr=2019-09-07, revisedDate=1575043200000, revisedDateStr=2019-11-30, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264931666, onlineDateStr=2026-10-29, pubDate=1587312000000, pubDateStr=2020-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264931666, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264931666, creator=13701087609, updateTime=1793264931666, updator=13701087609, issue=Issue{id=1322612228126265395, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='4', pageStart='463', pageEnd='614', issueExtLink='null', onlineDate='null', pubDate='1587312000000', pubDateStr='2020-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264928132, creator='13701087609', updateTime=1793276729826, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322661728073138752, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612228126265395, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322661728073138753, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612228126265395, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=551, endPage=557, ext={EN=ArticleExt(id=1322612243129290931, articleId=1322612242953130162, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Reversible Storage of Lithium in Porous Biomass Silicon Decorated Silver Nanoparticles, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

A porous Si/Ag composite material derived by waste rice husk was synthesized via magnesiothermic reduction-silver mirror reaction. The structure, surface morphology and lithium storage performance were investigated. The results show that the particle sizes of obtained biomass silicon material with a porous structure are 10-20 nm, and the cycle performance, rate performance and specific capacity of the electrode all are improved by recombining silver nanoparticles. The capacity of electrode with the silver particles can retain 750.4 mA·h/g after 50 cycles, which is twice greater than that of graphite, and it is 370.2 mA·h/g greater than that of pure biomass silicon electrode. The biomass Si/Ag electrode exhibits the specific capacity of 618.3 mA·h/g at current density of 800 mA/g, which is higher than that of biomass silicon (380.2 mA·h/g), due to the higher conductivity of Si/Ag nanomaterial and excellent property of electrode/electrolyte interface.

, authors=Tao FANG, Shuai GAO, Xiaodu LIANG, Youcong LI, Xia ZHANG, Ting MA, Lixia LIAO, authorsList=Tao FANG, Shuai GAO, Xiaodu LIANG, Youcong LI, Xia ZHANG, Ting MA, Lixia LIAO, authorCompany=null, correspAuthors=Lixia LIAO, authorNote=

FANG Tao (1979-), male, Ph.D., Associate Professor. E-mail:

, correspAuthorsNote=
LIAO Lixia (1979-), female, Ph.D., Associate Professor. E-mail:
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以废弃的谷壳为原料,通过镁热还原-银镜反应法成功制备了多孔硅/银复合纳米材料,并研究其结构形貌及储锂性能。结果表明:采用谷壳为原料获得的硅/银复合材料为纳米多孔结构,其粒径约为10~20 nm,纳米银的原位复合可显著提高电极的循环稳定性能、倍率性能和比容量。原位纳米银粒子复合后的Si/Ag电极50次循环后的容量依然能维持750.4 mA·h/g,为石墨类碳材料容量的2倍以上,较生物质硅电极提高了370.2 mA·h/g,采用800 mA/g的电流密度进行大电流充放电时,Si/Ag电极表现出618.3 mA·h/g的可逆容量,远高于Si电极380.2 mA·h/g的容量。性能的改善缘于复合后本体材料较高的导电性和电极/电解液界面的优良性能。

, authors=方涛, 高帅, 梁晓杜, 李幼聪, 张霞, 马婷, 廖丽霞, authorsList=方涛, 高帅, 梁晓杜, 李幼聪, 张霞, 马婷, 廖丽霞, authorCompany=null, correspAuthors=廖丽霞, authorNote=

方涛(1979—),男,博士,副教授。

, correspAuthorsNote=
廖丽霞(1979—),女,博士,副教授。
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方涛(1979—),男,博士,副教授。

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纳米银复合的多孔生物质硅材料的制备及储锂性能
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方涛 , 高帅 , 梁晓杜 , 李幼聪 , 张霞 , 马婷 , 廖丽霞
硅酸盐学报 | 2020,48(4): 551-557
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硅酸盐学报 | 2020 , 48 (4) : 551 -557
纳米银复合的多孔生物质硅材料的制备及储锂性能
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方涛 , 高帅, 梁晓杜, 李幼聪, 张霞, 马婷, 廖丽霞
作者信息
  • 东北林业大学化学化工与资源利用学院,哈尔滨 150040
通讯作者:
廖丽霞(1979—),女,博士,副教授。
作者简介:

方涛(1979—),男,博士,副教授。

Reversible Storage of Lithium in Porous Biomass Silicon Decorated Silver Nanoparticles
Tao FANG , Shuai GAO, Xiaodu LIANG, Youcong LI, Xia ZHANG, Ting MA, Lixia LIAO
Affiliations
  • College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040, China
  • Corresponding Author:
    LIAO Lixia (1979-), female, Ph.D., Associate Professor. E-mail:

    FANG Tao (1979-), male, Ph.D., Associate Professor. E-mail:

出版时间: 2020-04-20 doi: 10.14062/j.issn.0454-5648.20190620
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以废弃的谷壳为原料,通过镁热还原-银镜反应法成功制备了多孔硅/银复合纳米材料,并研究其结构形貌及储锂性能。结果表明:采用谷壳为原料获得的硅/银复合材料为纳米多孔结构,其粒径约为10~20 nm,纳米银的原位复合可显著提高电极的循环稳定性能、倍率性能和比容量。原位纳米银粒子复合后的Si/Ag电极50次循环后的容量依然能维持750.4 mA·h/g,为石墨类碳材料容量的2倍以上,较生物质硅电极提高了370.2 mA·h/g,采用800 mA/g的电流密度进行大电流充放电时,Si/Ag电极表现出618.3 mA·h/g的可逆容量,远高于Si电极380.2 mA·h/g的容量。性能的改善缘于复合后本体材料较高的导电性和电极/电解液界面的优良性能。

硅  /  生物质  /  锂离子电池  /  谷壳  /  镁热还原-银镜反应法

A porous Si/Ag composite material derived by waste rice husk was synthesized via magnesiothermic reduction-silver mirror reaction. The structure, surface morphology and lithium storage performance were investigated. The results show that the particle sizes of obtained biomass silicon material with a porous structure are 10-20 nm, and the cycle performance, rate performance and specific capacity of the electrode all are improved by recombining silver nanoparticles. The capacity of electrode with the silver particles can retain 750.4 mA·h/g after 50 cycles, which is twice greater than that of graphite, and it is 370.2 mA·h/g greater than that of pure biomass silicon electrode. The biomass Si/Ag electrode exhibits the specific capacity of 618.3 mA·h/g at current density of 800 mA/g, which is higher than that of biomass silicon (380.2 mA·h/g), due to the higher conductivity of Si/Ag nanomaterial and excellent property of electrode/electrolyte interface.

silicon  /  biomass  /  lithium ion battery  /  rice husk  /  magnesiothermic reduction-silver mirror reaction
方涛, 高帅, 梁晓杜, 李幼聪, 张霞, 马婷, 廖丽霞. 纳米银复合的多孔生物质硅材料的制备及储锂性能. 硅酸盐学报, 2020 , 48 (4) : 551 -557 . DOI: 10.14062/j.issn.0454-5648.20190620
Tao FANG, Shuai GAO, Xiaodu LIANG, Youcong LI, Xia ZHANG, Ting MA, Lixia LIAO. Reversible Storage of Lithium in Porous Biomass Silicon Decorated Silver Nanoparticles[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (4) : 551 -557 . DOI: 10.14062/j.issn.0454-5648.20190620
  • 国家自然科学基金(51602046)
  • 中央高校基本科研业务费项目(2572018BC30)
  • 黑龙江省博士后面上项目(LBH-Z14003; LBH-Z14014)
  • 大学生创新项目(201810225469)
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2020年第48卷第4期
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doi: 10.14062/j.issn.0454-5648.20190620
  • 接收时间:2019-09-07
  • 首发时间:2026-10-29
  • 出版时间:2020-04-20
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出版历史
  • 收稿日期:2019-09-07
  • 修回日期:2019-11-30
基金
国家自然科学基金(51602046)
中央高校基本科研业务费项目(2572018BC30)
黑龙江省博士后面上项目(LBH-Z14003; LBH-Z14014)
大学生创新项目(201810225469)
作者信息
    东北林业大学化学化工与资源利用学院,哈尔滨 150040

通讯作者:

廖丽霞(1979—),女,博士,副教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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