Article(id=1322609005441176542, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608967147172356, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190461, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1558972800000, receivedDateStr=2019-05-28, revisedDate=1562688000000, revisedDateStr=2019-07-10, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264159783, onlineDateStr=2026-10-29, pubDate=1582128000000, pubDateStr=2020-02-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264159783, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264159783, creator=13701087609, updateTime=1793264159783, updator=13701087609, issue=Issue{id=1322608967147172356, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='2', pageStart='147', pageEnd='324', issueExtLink='null', onlineDate='null', pubDate='1582128000000', pubDateStr='2020-02-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264150653, creator='13701087609', updateTime=1793276939599, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322662607933255748, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608967147172356, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322662607933255749, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608967147172356, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=195, endPage=203, ext={EN=ArticleExt(id=1322609005621531615, articleId=1322609005441176542, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Capacity Fading Mechanism and Modification Methods of Nickel-rich Ternary Cathode Materials, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Nickel-rich ternary cathode materials are the preferred cathode materials for large power lithium ion batteries due to their high capacity and high power. However, high nickel ternary cathode materials have some disadvantages, such as poor cyclic stability and fast capacity fading. It is indicated that cationic mixing, precipitation of transition metal element, oxygen vacancy, etc. are direct factors causing the material phase transformation, while interfacial film, overcharge, microcrack, etc. can further accelerate the material capacity fading. The existing modification technologies, such as element doping, surface coating and material composite, can inhibit the capacity fading of materials. In this review, the capacity fading mechanism and modification methods of high nickel ternary materials in recent years were represented, and a outlook for its future development was prospected.

, authors=Bo WANG1, Feilong ZHANG1, Ling AI1, Chao WANG1, Shiyou LI1, 2, authorsList=Bo WANG, Feilong ZHANG, Ling AI, Chao WANG, Shiyou LI, authorCompany=null, correspAuthors=Shiyou LI, authorNote=

WANG Bo (1995-), male, Master candidate. E-mail:

, correspAuthorsNote=
LI Shiyou (1980-), male, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322609005906744288, articleId=1322609005441176542, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=高镍三元正极材料容量衰减机理及改性方法, columnId=1263922774356181565, journalTitle=硅酸盐学报, columnName=综合评述, runingTitle=null, highlight=null, articleAbstract=

高镍三元正极材料因高容量、高功率等优势已成为大型动力锂离子电池的首选正极材料。然而,高镍三元正极材料存在循环稳定性差、容量衰减快等缺点。最新研究指出阳离子混排、过渡金属元素析出、氧空位等是造成材料相变的直接原因,而界面膜、过充、微裂纹等能进一步加速材料的容量衰减;元素掺杂、表面包覆和材料复合等作为当下最主流的改性技术,能显著抑制材料的容量衰减。本文综述了高镍三元材料容量衰减机理以及改性研究的现状,同时对其今后的发展方向做出了展望。

, authors=王博1, 张飞龙1, 艾灵1, 王超1, 李世友1, 2, authorsList=王博, 张飞龙, 艾灵, 王超, 李世友, authorCompany=null, correspAuthors=李世友, authorNote=

王博(1995—),男,硕士研究生。

, correspAuthorsNote=
李世友(1980—),男,博士,教授。
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WANG Bo (1995-), male, Master candidate. E-mail:

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王博(1995—),男,硕士研究生。

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高镍三元正极材料容量衰减机理及改性方法
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王博 1 , 张飞龙 1 , 艾灵 1 , 王超 1 , 李世友 1, 2
硅酸盐学报 | 综合评述 2020,48(2): 195-203
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硅酸盐学报 |综合评述 2020 , 48 (2) : 195 -203
高镍三元正极材料容量衰减机理及改性方法
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王博1 , 张飞龙1, 艾灵1, 王超1, 李世友1, 2
作者信息
  • 1.兰州理工大学石油化工学院,锂离子电池电解液材料工程实验室,兰州 730050
  • 2.中国科学院青海盐湖研究所,盐湖资源化学重点实验室,西宁 810001
通讯作者:
李世友(1980—),男,博士,教授。
作者简介:

王博(1995—),男,硕士研究生。

Capacity Fading Mechanism and Modification Methods of Nickel-rich Ternary Cathode Materials
Bo WANG1 , Feilong ZHANG1, Ling AI1, Chao WANG1, Shiyou LI1, 2
Affiliations
  • 1.Laboratory of Materials and Electroiyte for Lithium Batteries, School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou 730050, China
  • 2.Key Laboratory of Salt Lake Resources Chemistry, Qinghai Salt Lake Institute, Chinese Academy of Sciences, Xining 810001, China
  • Corresponding Author:
    LI Shiyou (1980-), male, Ph.D., Professor. E-mail:

    WANG Bo (1995-), male, Master candidate. E-mail:

出版时间: 2020-02-20 doi: 10.14062/j.issn.0454-5648.20190461
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高镍三元正极材料因高容量、高功率等优势已成为大型动力锂离子电池的首选正极材料。然而,高镍三元正极材料存在循环稳定性差、容量衰减快等缺点。最新研究指出阳离子混排、过渡金属元素析出、氧空位等是造成材料相变的直接原因,而界面膜、过充、微裂纹等能进一步加速材料的容量衰减;元素掺杂、表面包覆和材料复合等作为当下最主流的改性技术,能显著抑制材料的容量衰减。本文综述了高镍三元材料容量衰减机理以及改性研究的现状,同时对其今后的发展方向做出了展望。

高镍三元正极材料  /  相变  /  容量衰减  /  改性  /  锂离子电池

Nickel-rich ternary cathode materials are the preferred cathode materials for large power lithium ion batteries due to their high capacity and high power. However, high nickel ternary cathode materials have some disadvantages, such as poor cyclic stability and fast capacity fading. It is indicated that cationic mixing, precipitation of transition metal element, oxygen vacancy, etc. are direct factors causing the material phase transformation, while interfacial film, overcharge, microcrack, etc. can further accelerate the material capacity fading. The existing modification technologies, such as element doping, surface coating and material composite, can inhibit the capacity fading of materials. In this review, the capacity fading mechanism and modification methods of high nickel ternary materials in recent years were represented, and a outlook for its future development was prospected.

nickel-rich ternary cathode material  /  phase transformation  /  capacity fading  /  modification method  /  lithium ion battery
王博, 张飞龙, 艾灵, 王超, 李世友. 高镍三元正极材料容量衰减机理及改性方法. 硅酸盐学报, 2020 , 48 (2) : 195 -203 . DOI: 10.14062/j.issn.0454-5648.20190461
Bo WANG, Feilong ZHANG, Ling AI, Chao WANG, Shiyou LI. Capacity Fading Mechanism and Modification Methods of Nickel-rich Ternary Cathode Materials[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (2) : 195 -203 . DOI: 10.14062/j.issn.0454-5648.20190461
  • 国家自然科学基金(21566021; 21766017)
  • 甘肃省科技重大专项(17ZD2GC011)
  • 甘肃省高等学校科技成果转化项目(2017D-04)
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2020年第48卷第2期
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doi: 10.14062/j.issn.0454-5648.20190461
  • 接收时间:2019-05-28
  • 首发时间:2026-10-29
  • 出版时间:2020-02-20
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出版历史
  • 收稿日期:2019-05-28
  • 修回日期:2019-07-10
基金
国家自然科学基金(21566021; 21766017)
甘肃省科技重大专项(17ZD2GC011)
甘肃省高等学校科技成果转化项目(2017D-04)
作者信息
    1.兰州理工大学石油化工学院,锂离子电池电解液材料工程实验室,兰州 730050
    2.中国科学院青海盐湖研究所,盐湖资源化学重点实验室,西宁 810001

通讯作者:

李世友(1980—),男,博士,教授。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20190461
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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