Article(id=1322608932133122267, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190301, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1557158400000, receivedDateStr=2019-05-07, revisedDate=1562774400000, revisedDateStr=2019-07-11, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264142306, onlineDateStr=2026-10-29, pubDate=1579449600000, pubDateStr=2020-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264142306, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264142306, creator=13701087609, updateTime=1793264142306, updator=13701087609, issue=Issue{id=1322608929100649011, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='1', pageStart='1', pageEnd='146', issueExtLink='null', onlineDate='null', pubDate='1579449600000', pubDateStr='2020-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264141583, creator='13701087609', updateTime=1793276771816, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322661904204542961, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322661904208737266, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=21, endPage=27, ext={EN=ArticleExt(id=1322608932321865948, articleId=1322608932133122267, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Fluorescence Properties of Cu-In-Zn-S Quantum Dots by One-step Aqueous Phase Method, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Cu-In-Zn-S(CIZS) quaternary quantum dots (QDs) were prepared via a facile one-step method in aqueous solution. The effects of reaction temperature, cationic concentration and pH value of precursor solution on the phase composition, microscopic morphology and photoluminescence (PL) property were investigated by X-ray diffraction, transmission electron microscopy and fluorescence spectrophotometry. The results show that the crystallinity of QDs can be improved as the reaction temperature is increased, resulting in the increase of PL intensity. The PL intensity of CIZS QDs becomes the maximum value at 95 ℃. The particle size of CIZS QDs gradually decreases with the increase of cationic concentration, causing a blue shift of PL peaks from 634 nm to 617 nm. The optimized cationic concentration of precursor is 1.5 mmol/L. Moreover, the surface defects are effectively passivated by ligands at pH value of 5.0, resulting in the intense emission intensity. Based on the results by Fourier transform infrared spectroscopy, there are lots of functional groups on the surface of QDs, having a superior water solubility of QDs. The CIZS QDs have a promising application prospect in bio-imaging field.

, authors=Yanqiao XU1, Ting CHEN1, 2, Lianjun WANG2, 3, Wan JIANG2, 3, Weihui JIANG1, 2, Zhixiang XIE1, authorsList=Yanqiao XU, Ting CHEN, Lianjun WANG, Wan JIANG, Weihui JIANG, Zhixiang XIE, authorCompany=null, correspAuthors=Ting CHEN, authorNote=

XU Yanqiao (1992-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
CHEN Ting (1984-), female, Ph.D., Associate Professor. E-mail:
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采用简单的一步法制备了水溶性Cu-In-Zn-S(CIZS)四元量子点,利用X射线衍射仪、透射电子显微镜和荧光光谱仪等测试手段研究了反应温度、阳离子浓度和前驱体溶液pH值对样品的物相组成、显微形貌以及荧光性能的影响规律。结果表明:随着反应温度的升高,量子点的结晶度逐渐提高,荧光强度显著增强,当反应温度为95 ℃时,荧光强度达到了最高值;随着阳离子浓度的逐渐增大,量子点的粒径逐渐减小,导致其发光峰位由634 nm蓝移至617 nm,当阳离子浓度为1.5 mmol/L时,量子点的荧光强度最高。此外,当溶液pH值=5.0时,配体对量子点的表面钝化效果最佳,荧光强度达到最高值。红外光谱表明,量子点表面存在多种功能基团,赋予了量子点优异的水溶性,因此在生物成像领域具有广阔的应用前景。

, authors=徐彦乔1, 陈婷1, 2, 王连军2, 3, 江莞2, 3, 江伟辉1, 2, 谢志翔1, authorsList=徐彦乔, 陈婷, 王连军, 江莞, 江伟辉, 谢志翔, authorCompany=null, correspAuthors=陈婷, authorNote=

徐彦乔(1992—),男,博士研究生。

, correspAuthorsNote=
陈婷(1984—),女,博士,副教授。
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一步法水相制备Cu-In-Zn-S量子点及其荧光性能
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徐彦乔 1 , 陈婷 1, 2 , 王连军 2, 3 , 江莞 2, 3 , 江伟辉 1, 2 , 谢志翔 1
硅酸盐学报 | 2020,48(1): 21-27
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硅酸盐学报 | 2020 , 48 (1) : 21 -27
一步法水相制备Cu-In-Zn-S量子点及其荧光性能
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徐彦乔1 , 陈婷1, 2 , 王连军2, 3, 江莞2, 3, 江伟辉1, 2, 谢志翔1
作者信息
  • 1.景德镇陶瓷大学材料科学与工程学院,江西 景德镇 333001
  • 2.国家日用及建筑陶瓷工程技术研究中心,江西 景德镇 333001
  • 3.东华大学材料科学与工程学院,上海 201620
通讯作者:
陈婷(1984—),女,博士,副教授。
作者简介:

徐彦乔(1992—),男,博士研究生。

Preparation and Fluorescence Properties of Cu-In-Zn-S Quantum Dots by One-step Aqueous Phase Method
Yanqiao XU1 , Ting CHEN1, 2 , Lianjun WANG2, 3, Wan JIANG2, 3, Weihui JIANG1, 2, Zhixiang XIE1
Affiliations
  • 1.School of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333001, Jiangxi, China
  • 2.National Engineering Research Center for Domestic & Building Ceramics, Jingdezhen 333001, Jiangxi, China
  • 3.College of Materials Science and Engineering, Donghua University, Shanghai 201620, China
  • Corresponding Author:
    CHEN Ting (1984-), female, Ph.D., Associate Professor. E-mail:

    XU Yanqiao (1992-), male, Doctoral candidate. E-mail:

出版时间: 2020-01-20 doi: 10.14062/j.issn.0454-5648.20190301
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采用简单的一步法制备了水溶性Cu-In-Zn-S(CIZS)四元量子点,利用X射线衍射仪、透射电子显微镜和荧光光谱仪等测试手段研究了反应温度、阳离子浓度和前驱体溶液pH值对样品的物相组成、显微形貌以及荧光性能的影响规律。结果表明:随着反应温度的升高,量子点的结晶度逐渐提高,荧光强度显著增强,当反应温度为95 ℃时,荧光强度达到了最高值;随着阳离子浓度的逐渐增大,量子点的粒径逐渐减小,导致其发光峰位由634 nm蓝移至617 nm,当阳离子浓度为1.5 mmol/L时,量子点的荧光强度最高。此外,当溶液pH值=5.0时,配体对量子点的表面钝化效果最佳,荧光强度达到最高值。红外光谱表明,量子点表面存在多种功能基团,赋予了量子点优异的水溶性,因此在生物成像领域具有广阔的应用前景。

量子点  /  水相制备  /  荧光性能  /  铜铟锌硫

Cu-In-Zn-S(CIZS) quaternary quantum dots (QDs) were prepared via a facile one-step method in aqueous solution. The effects of reaction temperature, cationic concentration and pH value of precursor solution on the phase composition, microscopic morphology and photoluminescence (PL) property were investigated by X-ray diffraction, transmission electron microscopy and fluorescence spectrophotometry. The results show that the crystallinity of QDs can be improved as the reaction temperature is increased, resulting in the increase of PL intensity. The PL intensity of CIZS QDs becomes the maximum value at 95 ℃. The particle size of CIZS QDs gradually decreases with the increase of cationic concentration, causing a blue shift of PL peaks from 634 nm to 617 nm. The optimized cationic concentration of precursor is 1.5 mmol/L. Moreover, the surface defects are effectively passivated by ligands at pH value of 5.0, resulting in the intense emission intensity. Based on the results by Fourier transform infrared spectroscopy, there are lots of functional groups on the surface of QDs, having a superior water solubility of QDs. The CIZS QDs have a promising application prospect in bio-imaging field.

quantum dots  /  aqueous phase preparation  /  fluorescence property  /  copper-indium-zinc-sulfide
徐彦乔, 陈婷, 王连军, 江莞, 江伟辉, 谢志翔. 一步法水相制备Cu-In-Zn-S量子点及其荧光性能. 硅酸盐学报, 2020 , 48 (1) : 21 -27 . DOI: 10.14062/j.issn.0454-5648.20190301
Yanqiao XU, Ting CHEN, Lianjun WANG, Wan JIANG, Weihui JIANG, Zhixiang XIE. Preparation and Fluorescence Properties of Cu-In-Zn-S Quantum Dots by One-step Aqueous Phase Method[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (1) : 21 -27 . DOI: 10.14062/j.issn.0454-5648.20190301
  • 国家自然科学基金(51402135; 51432004; 51774096)
  • 江西省杰出青年人才资助计划项目(20171BCB23071)
  • 江西省自然科学基金(20181BAB216009; 20171BAB216008)
  • 江西省教育厅基金(GJJ180708; GJJ180707)
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2020年第48卷第1期
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文章信息
doi: 10.14062/j.issn.0454-5648.20190301
  • 接收时间:2019-05-07
  • 首发时间:2026-10-29
  • 出版时间:2020-01-20
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出版历史
  • 收稿日期:2019-05-07
  • 修回日期:2019-07-11
基金
国家自然科学基金(51402135; 51432004; 51774096)
江西省杰出青年人才资助计划项目(20171BCB23071)
江西省自然科学基金(20181BAB216009; 20171BAB216008)
江西省教育厅基金(GJJ180708; GJJ180707)
作者信息
    1.景德镇陶瓷大学材料科学与工程学院,江西 景德镇 333001
    2.国家日用及建筑陶瓷工程技术研究中心,江西 景德镇 333001
    3.东华大学材料科学与工程学院,上海 201620

通讯作者:

陈婷(1984—),女,博士,副教授。
参考文献
分享链接
https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20190301
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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