Article(id=1322608932133122267, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190301, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1557158400000, receivedDateStr=2019-05-07, revisedDate=1562774400000, revisedDateStr=2019-07-11, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264142306, onlineDateStr=2026-10-29, pubDate=1579449600000, pubDateStr=2020-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264142306, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264142306, creator=13701087609, updateTime=1793264142306, updator=13701087609, issue=Issue{id=1322608929100649011, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='1', pageStart='1', pageEnd='146', issueExtLink='null', onlineDate='null', pubDate='1579449600000', pubDateStr='2020-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264141583, creator='13701087609', updateTime=1793276771816, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322661904204542961, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322661904208737266, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=21, endPage=27, ext={EN=ArticleExt(id=1322608932321865948, articleId=1322608932133122267, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Fluorescence Properties of Cu-In-Zn-S Quantum Dots by One-step Aqueous Phase Method, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=
Cu-In-Zn-S(CIZS) quaternary quantum dots (QDs) were prepared via a facile one-step method in aqueous solution. The effects of reaction temperature, cationic concentration and pH value of precursor solution on the phase composition, microscopic morphology and photoluminescence (PL) property were investigated by X-ray diffraction, transmission electron microscopy and fluorescence spectrophotometry. The results show that the crystallinity of QDs can be improved as the reaction temperature is increased, resulting in the increase of PL intensity. The PL intensity of CIZS QDs becomes the maximum value at 95 ℃. The particle size of CIZS QDs gradually decreases with the increase of cationic concentration, causing a blue shift of PL peaks from 634 nm to 617 nm. The optimized cationic concentration of precursor is 1.5 mmol/L. Moreover, the surface defects are effectively passivated by ligands at pH value of 5.0, resulting in the intense emission intensity. Based on the results by Fourier transform infrared spectroscopy, there are lots of functional groups on the surface of QDs, having a superior water solubility of QDs. The CIZS QDs have a promising application prospect in bio-imaging field.
, authors=Yanqiao XU
1, Ting CHEN
1, 2, Lianjun WANG
2, 3, Wan JIANG
2, 3, Weihui JIANG
1, 2, Zhixiang XIE
1, authorsList=Yanqiao XU, Ting CHEN, Lianjun WANG, Wan JIANG, Weihui JIANG, Zhixiang XIE, authorCompany=null, correspAuthors=Ting CHEN, authorNote=
, correspAuthorsNote=
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322608932518998237, articleId=1322608932133122267, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=一步法水相制备Cu-In-Zn-S量子点及其荧光性能, columnId=null, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=
采用简单的一步法制备了水溶性Cu-In-Zn-S(CIZS)四元量子点,利用X射线衍射仪、透射电子显微镜和荧光光谱仪等测试手段研究了反应温度、阳离子浓度和前驱体溶液pH值对样品的物相组成、显微形貌以及荧光性能的影响规律。结果表明:随着反应温度的升高,量子点的结晶度逐渐提高,荧光强度显著增强,当反应温度为95 ℃时,荧光强度达到了最高值;随着阳离子浓度的逐渐增大,量子点的粒径逐渐减小,导致其发光峰位由634 nm蓝移至617 nm,当阳离子浓度为1.5 mmol/L时,量子点的荧光强度最高。此外,当溶液pH值=5.0时,配体对量子点的表面钝化效果最佳,荧光强度达到最高值。红外光谱表明,量子点表面存在多种功能基团,赋予了量子点优异的水溶性,因此在生物成像领域具有广阔的应用前景。
, authors=徐彦乔
1, 陈婷
1, 2, 王连军
2, 3, 江莞
2, 3, 江伟辉
1, 2, 谢志翔
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, correspAuthorsNote=
陈婷(1984—),女,博士,副教授。
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XU Yanqiao (1992-), male, Doctoral candidate. E-mail: xuyanqiao1234@163.com
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徐彦乔(1992—),男,博士研究生。
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徐彦乔(1992—),男,博士研究生。
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2.National Engineering Research Center for Domestic & Building Ceramics, Jingdezhen 333001, Jiangxi, China
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2.国家日用及建筑陶瓷工程技术研究中心,江西 景德镇 333001
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2.国家日用及建筑陶瓷工程技术研究中心,江西 景德镇 333001
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