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Article(id=1322612229699121800, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612191723897081, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190289, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1556812800000, receivedDateStr=2019-05-03, revisedDate=1558368000000, revisedDateStr=2019-05-21, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264928506, onlineDateStr=2026-10-29, pubDate=1584633600000, pubDateStr=2020-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264928506, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264928506, creator=13701087609, updateTime=1793264928506, updator=13701087609, issue=Issue{id=1322612191723897081, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='3', pageStart='325', pageEnd='462', issueExtLink='null', onlineDate='null', pubDate='1584633600000', pubDateStr='2020-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264919452, creator='13701087609', updateTime=1793277037156, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663017125368549, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612191723897081, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663017125368550, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612191723897081, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=428, endPage=433, ext={EN=ArticleExt(id=1322612229871088265, articleId=1322612229699121800, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=N/S co-doped Carbon Micro-spheres Anode Derived from Expired Compound Donkey-hide Gelatin for Sodium Ion Battery, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Hard carbon material was extracted from an expired composite donkey-hide gelatin pulp via hydrothermal carbonization pelletizing and subsequent pyrolysis reaction. The corresponding micro-morphology, element composition, structure and Na-storage performances were investigated. The results show that the obtained carbon material manifests a smooth microsphere-like morphology with the mean diameter of 4.3 μm, and N and S elements evenly distribute in carbon micro-spheres with a low degree of graphitization. The reversible discharge specific capacities are 225 and 180 mAh/g at 0.5 and 1.0 A/g for 500 cycles, respectively, and the reversible discharge specific capacity remains 108 mAh/g even at 2.0 A/g for 1 000 cycles, indicating the electrochemical Na-storage cycling performances at the large current density. The results could facilitate to promote the development of the circular economy mode of expired waste medicine and the green energy.

, authors=Xianxi LIU1, Zhiyu XU1, Chengyi YU2, Hongying HOU2, Dongdong LI2, Zhipeng DAI2, authorsList=Xianxi LIU, Zhiyu XU, Chengyi YU, Hongying HOU, Dongdong LI, Zhipeng DAI, authorCompany=null, correspAuthors=null, authorNote=

LIU Xianxi (1972-), male, Ph.D.,Associate Professor. E-mail:

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通过水热碳化成球及后续热解反应从过期复方阿胶浆中提取得到了硬碳材料，并研究了其微观形貌、元素组成、结构和储钠性能。结果表明，所得到的碳材料呈现平均直径约为4.3 μm的光滑微球形貌，氮/硫元素均匀地分布在碳微球中且石墨化程度较低；在0.5和1.0 A/g各循环500圈时，碳微球负极的可逆放电比容量分别稳定在225和180 mAh/g，即使在高达2.0 A/g的电流密度循环1 000圈时，放电比容量仍维持在108 mAh/g，表现了良好的高倍率循环储钠稳定性。无疑，该结果有助于推进过期废药的循环经济模式和绿色能源的发展。

, authors=刘显茜1, 徐梽宇1, 余成义2, 侯宏英2, 李栋栋2, 代志鹏2, authorsList=刘显茜, 徐梽宇, 余成义, 侯宏英, 李栋栋, 代志鹏, authorCompany=null, correspAuthors=null, authorNote=

刘显茜（1972—），男，博士，副教授。

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LIU Xianxi (1972-), male, Ph.D.,Associate Professor. E-mail:

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LIU Xianxi (1972-), male, Ph.D.,Associate Professor. E-mail:

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刘显茜（1972—），男，博士，副教授。

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刘显茜（1972—），男，博士，副教授。

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用于钠离子电池的过期复方阿胶浆衍生的氮/硫共掺杂硬碳微球负极
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刘显茜 1 , 徐梽宇 1 , 余成义 2 , 侯宏英 2 , 李栋栋 2 , 代志鹏 2
硅酸盐学报 | 2020,48(3): 428-433
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硅酸盐学报 | 2020 , 48 (3) : 428 -433
用于钠离子电池的过期复方阿胶浆衍生的氮/硫共掺杂硬碳微球负极
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刘显茜1 , 徐梽宇1, 余成义2, 侯宏英2, 李栋栋2, 代志鹏2
作者信息
  • 1.昆明理工大学机电工程学院，昆明 650093
  • 2.昆明理工大学材料科学与工程学院，昆明 650093
作者简介:

刘显茜（1972—），男，博士，副教授。

N/S co-doped Carbon Micro-spheres Anode Derived from Expired Compound Donkey-hide Gelatin for Sodium Ion Battery
Xianxi LIU1 , Zhiyu XU1, Chengyi YU2, Hongying HOU2, Dongdong LI2, Zhipeng DAI2
Affiliations
  • 1.Faculty of Mechanical and Electrical Engineering, Kunming University of Science and Technology, Kunming 650093, China
  • 2.Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China

    • LIU Xianxi (1972-), male, Ph.D.,Associate Professor. E-mail:

出版时间: 2020-03-20 doi: 10.14062/j.issn.0454-5648.20190289
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通过水热碳化成球及后续热解反应从过期复方阿胶浆中提取得到了硬碳材料，并研究了其微观形貌、元素组成、结构和储钠性能。结果表明，所得到的碳材料呈现平均直径约为4.3 μm的光滑微球形貌，氮/硫元素均匀地分布在碳微球中且石墨化程度较低；在0.5和1.0 A/g各循环500圈时，碳微球负极的可逆放电比容量分别稳定在225和180 mAh/g，即使在高达2.0 A/g的电流密度循环1 000圈时，放电比容量仍维持在108 mAh/g，表现了良好的高倍率循环储钠稳定性。无疑，该结果有助于推进过期废药的循环经济模式和绿色能源的发展。

过期复方阿胶浆  /  回收  /  氮/硫共掺杂  /  碳微球  /  储钠性能

Hard carbon material was extracted from an expired composite donkey-hide gelatin pulp via hydrothermal carbonization pelletizing and subsequent pyrolysis reaction. The corresponding micro-morphology, element composition, structure and Na-storage performances were investigated. The results show that the obtained carbon material manifests a smooth microsphere-like morphology with the mean diameter of 4.3 μm, and N and S elements evenly distribute in carbon micro-spheres with a low degree of graphitization. The reversible discharge specific capacities are 225 and 180 mAh/g at 0.5 and 1.0 A/g for 500 cycles, respectively, and the reversible discharge specific capacity remains 108 mAh/g even at 2.0 A/g for 1 000 cycles, indicating the electrochemical Na-storage cycling performances at the large current density. The results could facilitate to promote the development of the circular economy mode of expired waste medicine and the green energy.

expired donkey-hide gelatin medicine  /  recovery  /  nitrogen/sulfur co-doping  /  hard carbon micro-spheres  /  sodium storage performances
刘显茜, 徐梽宇, 余成义, 侯宏英, 李栋栋, 代志鹏. 用于钠离子电池的过期复方阿胶浆衍生的氮/硫共掺杂硬碳微球负极. 硅酸盐学报, 2020 , 48 (3) : 428 -433 . DOI: 10.14062/j.issn.0454-5648.20190289
Xianxi LIU, Zhiyu XU, Chengyi YU, Hongying HOU, Dongdong LI, Zhipeng DAI. N/S co-doped Carbon Micro-spheres Anode Derived from Expired Compound Donkey-hide Gelatin for Sodium Ion Battery[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (3) : 428 -433 . DOI: 10.14062/j.issn.0454-5648.20190289
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  • 国家自然科学基金(51566006; 51363011)
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2020年第48卷第3期
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doi: 10.14062/j.issn.0454-5648.20190289
  • 接收时间：2019-05-03
  • 首发时间：2026-10-29
  • 出版时间：2020-03-20
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  • 收稿日期：2019-05-03
  • 修回日期：2019-05-21
基金
国家自然科学基金(51566006; 51363011)
作者信息
    1.昆明理工大学机电工程学院，昆明 650093
    2.昆明理工大学材料科学与工程学院，昆明 650093
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2种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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