Article(id=1322608942308507997, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190100, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1550678400000, receivedDateStr=2019-02-21, revisedDate=1554048000000, revisedDateStr=2019-04-01, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264144732, onlineDateStr=2026-10-29, pubDate=1579449600000, pubDateStr=2020-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264144732, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264144732, creator=13701087609, updateTime=1793264144732, updator=13701087609, issue=Issue{id=1322608929100649011, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='1', pageStart='1', pageEnd='146', issueExtLink='null', onlineDate='null', pubDate='1579449600000', pubDateStr='2020-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264141583, creator='13701087609', updateTime=1793276771816, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322661904204542961, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322661904208737266, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=73, endPage=78, ext={EN=ArticleExt(id=1322608942459502942, articleId=1322608942308507997, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Research Progress on Manganese Dissolution and Deposition Mechanism of Cathode Materials for Manganese-based Lithium Ion Batteries, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Manganese dissolution is one of the important factors that result in the deterioration of the performance of manganese based cathode materials. It directly causes the loss of electrode active materials and induces manganese depositing on the negative electrode surface along with the migration of manganese, leading to a series of side reactions and irreversible loss of capacity. The mechanisms of manganese dissolution and deposition were summarized and the effect of manganese dissolution and deposition on lithium batteries was analyzed. The methods to inhibit manganese dissolution and deposition were proposed, and the development of manganese-based cathode materials was prospected as well.

, authors=Wenbo LI1, 2, Shiyou LI1, 2, Tongtong GENG1, 2, Fengfeng PENG1, 2, Youwei LIANG1, 2, authorsList=Wenbo LI, Shiyou LI, Tongtong GENG, Fengfeng PENG, Youwei LIANG, authorCompany=null, correspAuthors=Shiyou LI, authorNote=

LI Wenbo (1990-), male, Master candidate. E-mail:

, correspAuthorsNote=
LI Shiyou (1980-), male, Ph.D., Professor. E-mail:
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锰溶解是造成锰基正极材料性能恶化的重要因素之一,它不仅直接引起电极活性材料的损失,还会随着锰的迁移而在负极表面进行沉积,进而引发一系列的副反应,造成电池容量的不可逆损失。总结了锰系锂离子电池正极材料的锰溶解及沉积机理,分析了其对电池性能的影响,提出了抑制锰溶解及沉积的方法,并对锰基正极材料的发展进行了展望。

, authors=李文博1, 2, 李世友1, 2, 耿彤彤1, 2, 彭峰峰1, 2, 梁有维1, 2, authorsList=李文博, 李世友, 耿彤彤, 彭峰峰, 梁有维, authorCompany=null, correspAuthors=李世友, authorNote=

李文博(1990—),男,硕士研究生。

, correspAuthorsNote=
李世友(1980—),男,教授。
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锰系锂离子电池正极材料的锰溶解及沉积机理研究进展
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李文博 1, 2 , 李世友 1, 2 , 耿彤彤 1, 2 , 彭峰峰 1, 2 , 梁有维 1, 2
硅酸盐学报 | 综合评述 2020,48(1): 73-78
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硅酸盐学报 |综合评述 2020 , 48 (1) : 73 -78
锰系锂离子电池正极材料的锰溶解及沉积机理研究进展
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李文博(1990—),男,硕士研究生。

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李文博1, 2 , 李世友1, 2 , 耿彤彤1, 2, 彭峰峰1, 2, 梁有维1, 2
作者信息
  • 1.兰州理工大学石油化工学院,兰州 730050
  • 2.甘肃省锂离子电池电解液材料工程实验室,兰州 730050
通讯作者:
李世友(1980—),男,教授。
作者简介:

李文博(1990—),男,硕士研究生。

Research Progress on Manganese Dissolution and Deposition Mechanism of Cathode Materials for Manganese-based Lithium Ion Batteries
Wenbo LI1, 2 , Shiyou LI1, 2 , Tongtong GENG1, 2, Fengfeng PENG1, 2, Youwei LIANG1, 2
Affiliations
  • 1.College of Petrochemical Technology, Lanzhou University of Technology, Lanzhou 730050, China
  • 2.Gansu Engineering Laboratory of Electrolyte Material for Lithium-ion Battery, Lanzhou 730050, China
  • Corresponding Author:
    LI Shiyou (1980-), male, Ph.D., Professor. E-mail:

    LI Wenbo (1990-), male, Master candidate. E-mail:

出版时间: 2020-01-20 doi: 10.14062/j.issn.0454-5648.20190100
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锰溶解是造成锰基正极材料性能恶化的重要因素之一,它不仅直接引起电极活性材料的损失,还会随着锰的迁移而在负极表面进行沉积,进而引发一系列的副反应,造成电池容量的不可逆损失。总结了锰系锂离子电池正极材料的锰溶解及沉积机理,分析了其对电池性能的影响,提出了抑制锰溶解及沉积的方法,并对锰基正极材料的发展进行了展望。

锂离子电池  /  锰基正极材料  /  锰溶解  /  锰沉积  /  机理

Manganese dissolution is one of the important factors that result in the deterioration of the performance of manganese based cathode materials. It directly causes the loss of electrode active materials and induces manganese depositing on the negative electrode surface along with the migration of manganese, leading to a series of side reactions and irreversible loss of capacity. The mechanisms of manganese dissolution and deposition were summarized and the effect of manganese dissolution and deposition on lithium batteries was analyzed. The methods to inhibit manganese dissolution and deposition were proposed, and the development of manganese-based cathode materials was prospected as well.

lithium ion battery  /  manganese-based cathode materials  /  manganese dissolution  /  manganese deposition  /  mechanism
李文博, 李世友, 耿彤彤, 彭峰峰, 梁有维. 锰系锂离子电池正极材料的锰溶解及沉积机理研究进展. 硅酸盐学报, 2020 , 48 (1) : 73 -78 . DOI: 10.14062/j.issn.0454-5648.20190100
Wenbo LI, Shiyou LI, Tongtong GENG, Fengfeng PENG, Youwei LIANG. Research Progress on Manganese Dissolution and Deposition Mechanism of Cathode Materials for Manganese-based Lithium Ion Batteries[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (1) : 73 -78 . DOI: 10.14062/j.issn.0454-5648.20190100
  • 国家自然科学基金(51502124; 21766017)
  • 白银市科技计划项目(2017-2-11G)
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2020年第48卷第1期
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doi: 10.14062/j.issn.0454-5648.20190100
  • 接收时间:2019-02-21
  • 首发时间:2026-10-29
  • 出版时间:2020-01-20
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  • 收稿日期:2019-02-21
  • 修回日期:2019-04-01
基金
国家自然科学基金(51502124; 21766017)
白银市科技计划项目(2017-2-11G)
作者信息
    1.兰州理工大学石油化工学院,兰州 730050
    2.甘肃省锂离子电池电解液材料工程实验室,兰州 730050

通讯作者:

李世友(1980—),男,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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