电源学报

鱿鱼墨基多孔碳/Fe₃O₄复合材料的合成及储锂特性

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程凤丽中国电源学会会员 ¹ , 郝恩超 ²

电源学报 | 新能源发电与储能 2026,24(7): 173-181

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电源学报 |新能源发电与储能 2026 , 24 (7) : 173 -181

鱿鱼墨基多孔碳/Fe₃O₄复合材料的合成及储锂特性

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郝恩超（1990—　），男，硕士。研究方向：锂离子电池产品开发。E-mail：240454845@qq.com。

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程凤丽中国电源学会会员¹, 郝恩超²

作者信息

^1.国投检测化工安全技术（山东）有限公司，济南　250102

^2.宁德新能源科技有限公司，宁德　352000

通讯作者:

程凤丽（1989—　），女，中国电源学会会员，通信作者，硕士。研究方向：新能源电极材料。E-mail：1351826942@qq.com。

作者简介:

郝恩超（1990—　），男，硕士。研究方向：锂离子电池产品开发。E-mail：240454845@qq.com。

Synthesis and Lithium Storage Properties of Squid Ink-based Porous Carbon/Fe₃O₄ Composite Material

Fengli CHENG Member, CPSS¹, Enchao HAO²

Affiliations

^1.SDIC Testing Chemical Safety Technology (Shan Dong) Co., Ltd., Jinan 250102, China

^2.Ningde Amperex Technology Limited, Ningde 352000, China

出版时间: 2026-07-30 doi: 10.13234/j.issn.2095-2805.2026.7.173

文章导航

摘要

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以鱿鱼墨为生物质碳源制备了具有高比表面积的多孔碳材料，并通过浸渍还原法制备出Fe₃O₄与鱿鱼墨基多孔碳HPBC（highly porous biomass carbon）的复合材料Fe₃O₄/HPBC。该材料在锂离子电池方面得到了较好的应用，据此研究不同铁离子含量和不同煅烧温度对其电化学性能的影响。最佳比例条件下，制备的Fe₃O₄/HPBC复合材料作为锂离子电池负极时，在0.2 A/g电流密度下首次放电和充电的比容量分别为1 590.0和961.0 mAh/g、库仑效率为60%，循环300圈后基本不衰减；在5.0 A/g电流密度下循环400圈后，放电比容量仍能达到484.0 mAh/g，高于制备的碳材料电极的放电比容量，这表明Fe₃O₄/HPBC电极在较大电流密度下，仍具有良好的储锂性能和循环稳定性。

关键词

鱿鱼墨 / Fe₃O₄ / 复合 / 锂离子电池

Abstract

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A porous carbon material with high specific surface area was prepared from squid ink as carbon source, and a composite material Fe₃O₄/HPBC of Fe₃O₄ and highly porous biomass carbon (HPBC) was prepared by immersion reduction method. The material was used in lithium-ion batteries. At the same time, the effects of different iron ion content and calcination temperature on the electrochemical properties of the composites were also studied. When the prepared Fe₃O₄/HPBC and carbon composite material is used as the negative electrode of lithium-ion batteries, the specific capacities of initial discharge and charge at 0.2 A/g current density are 1 590.0 and 961.0 mAh/g respectively, the coulombic efficiency is 60%, after 300 cycles the capacity without attenuation. After 400 cycles of 5.0 A/g current density, the specific discharge capacity can still reach 484.0 mAh/g, which is higher than the specific discharge capacity of the prepared carbon material electrode, indicating that the Fe₃O₄/HPBC electrode still has good lithium storage performance and cycle stability under large current densities.

Key words

Squid ink / Fe₃O₄ / composite / lithium-ion batteries

引用本文

程凤丽中国电源学会会员, 郝恩超. 鱿鱼墨基多孔碳/Fe₃O₄复合材料的合成及储锂特性. 电源学报, 2026 , 24 (7) : 173 -181 . DOI: 10.13234/j.issn.2095-2805.2026.7.173

Fengli CHENG, Enchao HAO. Synthesis and Lithium Storage Properties of Squid Ink-based Porous Carbon/Fe₃O₄ Composite Material[J]. Journal of Power Supply, 2026 , 24 (7) : 173 -181 . DOI: 10.13234/j.issn.2095-2805.2026.7.173

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2026年第24卷第7期

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文章信息

doi: 10.13234/j.issn.2095-2805.2026.7.173

接收时间：2024-05-14
首发时间：2026-10-29
出版时间：2026-07-30

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收稿日期：2024-05-14
修回日期：2024-09-20
录用日期：2024-09-27

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作者信息

^1.国投检测化工安全技术（山东）有限公司，济南　250102

^2.宁德新能源科技有限公司，宁德　352000

通讯作者:

程凤丽（1989—　），女，中国电源学会会员，通信作者，硕士。研究方向：新能源电极材料。E-mail：1351826942@qq.com。

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https://castjournals.cast.org.cn/joweb/dyxb/CN/10.13234/j.issn.2095-2805.2026.7.173

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2种不同金属材料的力学参数

科 Family	属数 Number of genus	种数 Number of species	占总种数比例 Percentage of total species (%)	属 Genus	种数 Number of species	占总种数比例 Percentage of total species (%)
鹅膏菌科Amanitaceae	2	11	5.26	鹅膏菌属 Amanita	10	4.78
小菇科 Mycenaceae	2	12	5.74	丝盖伞属 Inocybe	5	2.39
多孔菌科 Polyporaceae	8	14	6.70	蜡蘑属 Laccaria	5	2.39
红菇科 Russulaceae	3	23	11.00	小皮伞属 Marasmius	6	2.87
				小菇属 Mycena	11	5.26
				光柄菇属 Pluteus	5	2.39
				红菇属 Russula	17	8.13
				栓菌属 Trametes	5	2.39

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